Heat treating aluminum presents a unique concern due to the operating conditions of high temperature, chemical corrosion, mechanical abrasion, and temperature variation. Guest columnist Roger M. Smith, director of technical services at Plibrico Company, LLC, examines the critical role the refractory lining plays in the success of manufacturing aluminum, why a refractory is susceptible to cracking under extreme conditions, and how to select and prepare refractory linings to achieve a longer service life.
A significant concern when manufacturing aluminum metal is the practical service life of the furnace. The service life is driven by the refractory lining’s ability to resist the various operating conditions within the furnace, such as high temperature, temperature variation, chemical corrosion, and mechanical abrasion. Ideally, a single refractory composition would be capable of withstanding all these conditions and readily available at a low price. Unfortunately, this is rarely the case.
Proper refractory selection is often about finding the best balance between price, properties, and performance for the given application and operating conditions. A refractory capable of high strength and abrasion resistance is often susceptible to cracking caused by extreme temperature variations, commonly referred to as thermal shock. However, a material capable of withstanding thermal shock without catastrophic cracking may be vulnerable to chemical corrosion. Finding the best balance of material properties for each zone in each furnace is important for maximizing the service life of a furnace.
Refractory Under Attack — Requirements for Melting Aluminum
The refractory lining in an aluminum furnace (Figure 1) must endure various chemical reactions that occur while the furnace is in operation. There are three separate regions to consider: above, below, and at the melt line. Above the melt line, the refractory must withstand attack from various alkali vapors. Alkali vapors can be produced from flux used in the aluminum and from the combustion products used to heat the furnace. Below the melt line, the refractory must withstand molten aluminum. At the melt line, the region commonly referred to as the bellyband area, there is a triple point where the refractory, atmosphere, and aluminum interact.
The refractory below the melt line comes in direct contact with liquid aluminum when the furnace is in operation. This contact can create a chemical reaction zone where oxides on the surface of the refractory can be reduced, such as silica (SiO2) to form silicon. Conversely, aluminum can penetrate into the refractory lining either through the same redox reactions or through infiltration due to capillary forces.
Aluminum forms corundum (Al2O3) when it oxidizes. This results in a change of the crystal structure from face-centered cubic to hexagonal, which causes a significant volume expansion. When corundum is formed inside the refractory lining, the change in volume creates cracks, which lead to more infiltration and more cracks until the refractory lining ultimately fails.
Wetting the Refractory
One method for reducing the reaction zone is to prevent the aluminum from “wetting” the refractory (see Figure 2). A liquid’s ability to “wet” a surface is defined by the contact angle of the liquid. When the contact angle between the liquid and the surface is greater than 90 degrees, then the liquid is said to wet the surface. When the contact angle is less than 90 degrees, the liquid does not wet the surface. A liquid that does not wet the surface is analogous to water beading on a car that has been freshly waxed. When aluminum does not wet a refractory, it is not able to react with the refractory and is not able to penetrate the lining.
Various additives can be used to reduce aluminum’s tendency to wet a refractory. Some of the most used additives include barium, boron, or fluoride. They modify the surface chemistry of the refractory and reduce aluminum’s ability to react and penetrate. Using additives such as these greatly extends the effective service life of a refractory lining.
While non-wetting additives can be beneficial to extending the service life in areas where there is contact with molten aluminum, there are no benefits when not in aluminum contact. They do not protect from alkali attacks above the melt line. They do not enhance the abrasion resistance of the material. They do not improve the thermal shock resistance of the material. Furthermore, these additives are volatile. When exposed to temperatures above 1700°F (927°C), they begin to lose their effectiveness because they chemically react with other materials in the refractory and change. The additives can also be costly, which raises the price of the refractory compared to one with the same composition but without the additive.
The presence of non-wetting additives can have some negative effects on a refractory. Tests have shown that a 1% addition of a fluoride additive in a conventional castable can reduce the hot modulus of rupture (HMOR) by as much as 30% at 2000°F (1093°C). The effect can be even more significant in a low-cement castable. The loss in hot strength is likely attributed to the formation of a glassy phase induced by the additive. Fluoride and boron are both well-known glass formers and will form a glassy phase at the grain boundaries at high temperatures, which reduces the bond strength between individual grains and the overall strength of the bulk material.
Balancing Refractory Properties
The advantages and disadvantages of a refractory material should be considered when selecting materials for an aluminum furnace. The sidewalls of a furnace all come in direct contact with molten aluminum.
The upper sidewalls must be scraped to remove aluminum that splashes up to prevent corundum growth. The refractory selected for its sidewalls should be abrasion resistant to protect from mechanical scraping and non-wetting to protect from corundum growth. The hearth and well are submerged in aluminum, but they do not see the same level of abrasion as the sidewalls. The sub-hearth may see some molten aluminum but must also provide support, so a strong, non-wetting refractory should be used.
The door and sill will experience temperature fluctuations every time the door is opened, and they will be exposed to abrasion as the furnace is charged. Materials that are resistant to thermal shock and abrasion should be selected. The roof and superstructure need to be strong and resistant to alkali vapors. Backup insulation should be selected to reduce heat loss, but it should be of a composition that has moderate resistance to molten aluminum in case of refractory failure at the hot face.
In all these zones, the operating conditions of the specific furnace must be considered, and the balance of properties must be adjusted case-by-case. The primary failure modes must be identified, and materials should then be adjusted accordingly.
The Key to Refractory Selection
The operating conditions in an aluminum furnace require a refractory lining with different benefits in different zones. At the furnace door, the refractory can experience drastic fluctuations in temperature that can cause cracking. The upper sidewalls will develop scale that has to be scraped off, so the refractory needs to be abrasion resistant.
The lower sidewalls come in direct contact with molten aluminum and need to resist chemical attacks and aluminum penetration to avoid corundum growth. Finding a cost-effective refractory that can meet all these requirements is very difficult, but it can be done with sufficient research. Careful material selection that considers the needs and operating conditions of a particular furnace is important for maximizing the service life of a refractory lining.
About the Author:
Roger Smith is a seasoned professional in the refractory industry. With a master’s degree in Ceramic Engineering from the University of Missouri – Rolla, Roger has over 15 years of experience in the processing, development, and quality assurance of both traditional and advanced ceramics. He has a proven track record in developing innovative ceramic formulations, scaling up processes for commercial production, and optimizing manufacturing operations.
Three elements in the T6 aluminum heat treatment process — high temperature solution heat treatment, drastic temperature change in the water quench, and a long age hardening process — challenge accurate temperature monitoring. Thru-process technology gives in-house heat treaters the power to control these variables to overcome the unknowns. In the following Technical Tuesday article, Dr. Steve Offley, “Dr. O”, product marketing manager at PhoenixTM, examines the path forward through the challenges of aluminum heat treating.
In today’s automotive and general manufacturing markets, aluminum is increasingly becoming the material of choice, being lighter, safer, and more sustainable. Manufacturers looking to replace existing materials with aluminum are needing new methodology to prove that thermal processing of aluminum parts and products is done to specification, efficiently and economically.
To add strength to pure aluminum, alloys are developed by the addition of elements dissolved into solid solutions employing the T6 heat treatment process (Figure 1). The alloy atoms create obstacles to dislocate movement of aluminum atoms through the aluminum matrix. This gives more structural integrity and strength.
Process temperature control and uniformity is critical to the success of T6 heat treat to maximize the solubility of hardening solutes such as copper, magnesium, silicon, and zinc without exceeding the eutectic melting temperature. With a temperature difference of typically 9–15°F, knowing the accurate temperature of the product is essential. Control of the later quench process (Figure 1, Phase 3) is also critical not only to facilitate the alloy element precipitation phase but also to prevent unwanted part distortion/warping and risk of quench cracking.
T6 Process Monitoring Challenges
The T6 solution reheat process comes with many technical challenges where temperature profiling is concerned. The need to monitor all three of the equally important phases — solution treatment, quench, and the age hardening process — makes the trailing thermocouple methodology impossible.
Even when considering applying thru-process temperature profiling technology, sending the data logger through the process, protected in a thermal barrier (Figure 2), the T6 heat treat process comes with significant challenges. A system will not only need to protect against heat (up to 1020°F) over a long process duration but also withstand the rigors of being plunged into a water quench. Rapid temperature transitions create elevated risk of distortion and warping which need to be addressed to give a reliable and robust monitoring solution.
Certain monitoring systems can provide protection to the data logger at 1022°F for up to 20 hours (Figure 3).
Thermal Protection Technology
To meet the challenges of the T6 heat treat process, the conventional thermal barrier design employing microporous insulation is replaced with a water tank design, with thermal protection using an evaporative phase change temperature control principle. Evaporative technology uses boiling water to keep the high temperature data logger (maximum operating temperature of 230°F) at a stable operating temperature of 212°F as the water changes phase from liquid to steam. The advantage of evaporative technology is that a physically smaller barrier is often possible. It is estimated that with a like for like size (volume) and weight, an evaporative barrier will provide in the region of twice the thermal protection of a standard thermal barrier with microporous insulation and heat sink. The level of thermal protection can be adjusted by changing the capacity of the water tank and the volume of water. Increasing the volume of water increases the duration at which the T6 temperature barrier will maintain the data logger temperature of 212°F before it is depleted by evaporation losses.
The TS06 thermal barrier design (Figure 4) incorporates a further level of protection with an outer layer of insulation blanket contained within a structural outer metal cage. The key role of this material is to act as an insulative layer around the water tank to reduce the risk of structural distortion from rapid temperature changes both positive and negative in the T6 process.
Obviously, the evaporative loss rate of water is governed by the water tank geometry. A cube shaped tank will provide the best performance, but this may need to be adapted to meet process height restrictions. A TS06 thermal barrier with dimensions 8.5 x 18.6 x 25.2 inches (H x W x L) offering a water capacity of 3.5 US gallons provides 11 hours of protection at 1022°F. A larger TS06 with approximately twice the capacity 12.2 x 18.6 x 25.2 inches (H x W x L) and 7.7 US gallons gives approximately twice the protection (20 hours at 1022°F).
Innovative IP67 Sealing Design
Passing through the water quench, the data logger needs to be protected from water damage. This is achieved in the system design by combining a fully IP67 sealed data logger case and water tank front face plate through which the thermocouples exit. Traditionally in heat treatment applications, mineral insulated thermocouples are sealed using robust metal compression fittings. Although reliable, the compression seals are difficult to use, requiring long set-up times. The whole uncoiled straight cable length must be passed through the tight fitting which, for the 10 x 13 ft thermocouples, takes some patience. Thermocouples can be used and installed for multiple runs, if undamaged. Unfortunately, as the ferrule in the compression fitting bites into the MI cable, removal of the cable requires the thermocouple to be cut, preventing reuse.
To overcome the frustrations of compression fitting, an alternative innovative thermocouple sealing mechanism has been designed for use on the T6 thermal barrier (Figure 5).
Thermocouples can be slotted easily and quickly, tool free, into a precision cut rubber gasket without any need to uncoil the thermocouple completely. The rubber gasket has a unique bi-directional seal, allowing both sealing of each thermocouple but also sealing of the clamp face plate to the data logger tray, which is then secured to the water tank with a further silicone gasket seal. The new seal design allows thermocouples to be uninstalled and reused, reducing operating costs significantly.
Accurate Process Data considerations
The T6 applications come with a series of monitoring challenges which need to be considered carefully to guarantee the quality of the data obtained. Although the complete process time of the three phases can reach up to 10 hours, it is necessary to use a rapid sample interval (seconds) to provide a sufficient resolution. The data logger is designed to facilitate this with a minimum sample interval of 0.2 seconds over 20 channels and memory size of 3.8 million data points, allowing complete monitoring of the entire process. A sample interval of 0.2 seconds provides sufficient data points on the rapid quench cooling curve. The high resolution allows full analysis and optimization of the quench rate to achieve required metallurgical transitions yet avoid distortion or quench cracking risks.
Employing the phased evaporation thermal barrier design, the high temperature data logger with maximum operating temperature of 230°F will operate safely at 212°F. During the profile run, the data logger internal temperature will increase from ambient temperature to 212°F. To allow the thermocouple to accurately record temperature, the data logger offers a sophisticated cold junction compensation method, correcting the thermocouple read out (hot junction) for anticipated internal data logger temperature changes.
Data logger and thermocouple calibration data covering the complete measurement range (not just a single designated temperature) can be used to create detailed correction factor files. Correction factors are calculated by interpolation between two known calibration points using the linear method as approved by CQI-9 and AMS2750G. This method ensures that all profile data is corrected to the highest possible accuracy.
Addressing Real-Time, Thru-Process Temperature Monitoring Challenges
For a process time as long as the T6, real-time monitoring capability is a significant benefit. The unique two-way RF telemetry system used on the PhoenixTM system helps address the technical challenges of the three separate stages of the process. The RF signal can be transmitted from the data logger through a series of routers linked back to the main coordinator connected to the monitoring PC. The wirelessly connected routers are located at convenient points in the process (solution treatment furnace, quench tank, aging furnace) to capture all live data without any inconvenience of routing communication cables.
A major challenge in the T6 process is the quench step from an RF telemetry perspective. An RF signal cannot escape from water in the quench tank. To overcome this limitation, a “catch up” feature is implemented. Once the system exits the quench and the RF signal is re-established, any previously missing data is retransmitted guaranteeing full process coverage.
Process Quality Assurance and Validation
In the automotive industry, many operations will be working to the CQI-9 special process heat treat system assessment accreditation. As defined by the pyrometry standard, operators need to validate the accuracy and uniformity of the furnace work zone by employing a temperature uniformity survey (TUS).
The thru-process monitoring principle allows for an efficient method by which the TUS can be performed employing a TUS frame to position a defined number of thermocouples over the specific working zone of the furnace (product basket). As defined in the standard with particular reference to application assessment process Table C (aluminum heat treating), the uniformity for both the solution heat treatment and aging furnace needs to be proven to satisfy ±10°F of the threshold temperature during the soak time.
Complementing the TUS system, the Thermal View Survey software provides a means by which the full survey can be set up automatically allowing routine full analysis and reporting to the CQI-9 specification as shown in Figure 6.
Interestingly, a significant further benefit of the thru-process principle is that by collecting process data for the whole process, many of the additional requirements of the process Table C can be achieved with reference to the quench. From the profile trace, key criteria such as quench media temperature, quench delay time, and quench cooling curve can be measured and reported with full traceability during the production run.
Summary
To fully understand, control, and optimize the T6 heat treat process, it is essential the entire process is monitored. Thru-process monitoring solutions, designed specifically, allow not only product temperature profiling of all the solution heat treatment, water quench, and age hardening phases, but also comprehensive temperature uniformity surveying to comply with CQI-9.
About the Author:
Dr. Steve Offley, “Dr. O,” has been the product marketing manager at PhoenixTM for the last five years after a career of over 25 years in temperature monitoring focusing on the heat treatment, paint, and general manufacturing industries. A key aspect of his role is the product management of the innovative PhoenixTM range of thru-process temperature and optical profiling and TUS monitoring system solutions.
Precise heat treating is essential to enable components to withstand space exploration. In this Technical Tuesday, Mike Grande, vice president of Sales at Wisconsin Oven Corporation, discusses the role of aluminum solution treatment and aluminum aging in heat treating space exploration components.
This column was first released in Heat Treat Today March 2024 Aerospace Heat Treatprint edition.
In space exploration, the various parts, electronic components, and materials used to make the rockets, crew capsules, rovers, and other equipment, are subjected to brutal extremes of temperature, vacuum, and radiation. In order to withstand these extreme environments without failure, the parts must be manufactured to very tight tolerances and precisely heat treated. Therefore, convection heat treatment emerges as a critical process in the manufacturing of space exploration components and materials, offering tight control over temperature profiles and the microstructure of materials.
Heat treatment involves heating a material to a specific temperature, holding it at that temperature for a certain duration, and then cooling it down at a controlled rate, which can be rapid or gradual, depending on the objective. The purpose of heat treatment is to improve the material’s mechanical properties, such as strength, ductility, and toughness. Probably the most common metal used in space exploration is aluminum. It is an excellent choice for spacecraft components because it is lightweight, durable, and has excellent thermal conductivity, which is necessary for components that need to dissipate heat.
The first stage of the Falcon 9, for example, utilizes four legs used during landing. They are manufactured from an extremely light, rigid, aluminum honeycomb material that also contains carbon fiber and has a very high strength to weight ratio. Another aluminum component common in space exploration is gas transfer tubes, used to transfer gases, such as methane, between chambers in the interior of rocket propulsion systems. Additionally, there are composite overwrapped pressure vessels (COPVs), which carry compressed fuels such as hydrogen and oxygen, among other gases. These are made of an aluminum tank covered with filament-wound, resin-impregnated composite material, which forms an extremely robust structure capable of withstanding the high pressures created by compressed gases and the rigors of high-speed propulsion. For aluminum to be useful in space applications, it must be heat treated to give it the strength and durability required.
Aluminum Solution Treatment
Since aluminum has such widespread use in space exploration, aluminum heat treatment plays a central role in this industry, with solution treatment and aging being the most common heat treatments utilized. All aluminum materials that require high strength are solution heat treated, then subsequently aged, in two separate heat treat processes. The purpose of solution heat treatment is to evenly dissolve the alloys contained in the aluminum, such as manganese, magnesium, copper, zinc, and silicon, and then rapidly quench it to retain the grain structure. The aluminum alloy is heated and held at a temperature of 800°F to 1000°F (420°C to 540°C), which is just below its melting point. The aluminum is then quenched in water or a water/glycol mixture quickly (within 7 to 15 seconds) to essentially “freeze” the microstructure before the alloying elements can redistribute themselves.
Aluminum Aging
After quenching, aluminum is precipitation hardened. Also known as artificial aging, this process involves heating the aluminum at a lower temperature, typically in the range of 200°F to 400°F (93°C to 204°C) for several hours. This final process dramatically increases the hardness, yield strength, and ultimate strength of the aluminum, making it suitable for use in space applications.
The above is just a sample of the many types of heat treatments for materials used in space exploration. Other examples are annealing, tempering, normalizing, and hydrogen embrittlement relief, to name a few. In conclusion, heat treatment plays a critical role in the manufacturing of parts used in space exploration and is essential to the reliability and safety of space missions.
About the Author
Mike Grande has a 30+ year background in the heat processing industry, including ovens, furnaces, and infrared equipment. He has a BS in mechanical engineering from University of Wisconsin-Milwaukee and received his certification as an Energy Manager (CEM) from the Association of Energy Engineers in 2009. Mike is the vice president of Sales at Wisconsin Oven Corporation.
For more information: Contact sales@wisoven.com.
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Are there rapid changes in the North American aluminum industry to accommodate trending technology, or does the aluminum market have a different focus? Enjoy this Technical Tuesday article, in which six industry players responded to the following survey from Heat Treat Today’s editorial team in August 2023.
Steady and Increasing Melters’ Demand
Is demand increasing or decreasing for aluminum processing/melting equipment?
AFC-Holcroft: “Yes, we continue to see opportunities for a variety of furnaces for T5, T6, and other aluminum heat treating processes. We recently signed a license agreement with Sanken Sangyo in Japan to offer their aluminum rotary furnace designs in the U.S. and Canada.”
Can-Eng Furnaces Intl., Ltd.: “Yes, particularly in finished component heat treatment systems (T4, T5, T6, and T7 processes). The processing demand is coming from new vehicle (ICE, hybrid, electric) model line-ups that are focusing heavily on lightweighting body in white (BIW), structural, and suspension components that are being converted from steel to aluminum.”
Lindberg/MPH: “We have seen an increase in aluminum scrap melting in the recent past with larger capacity melters being quoted.”
Premier Furnace Specialists: “We’re seeing a steady demand for aluminum processing equipment. Typically, our clients are requesting either aluminum solution furnaces, drop bottom furnaces, or pre-heat furnaces. There has been an increased demand for larger furnace chamber sizes and heavier load capacities as more customers are requesting furnaces that can handle a variety of materials, temperature ranges, and processes. It seems the aerospace industry is driving most of the demand at the moment.”
SECO/WARWICK: “On the molten metal side of the SECO/WARWICK business, there are a few significant projects out there which are active, and the level of inquiries is good!”
Wisconsin Oven: “We have seen an uptick in aluminum solution treat and aging equipment in recent years.”
Kelley Shreve General Manager Lindberg/MPHJacob Laird Mechanical Engineer Premier Furnace Specialists, Inc./BeaverMaticDan Peterson Product Manager Molten Metal Furnaces SECO/WARWICK Corp.Mike Grande Vice President of Sales Wisconsin Oven Corporation
AM/3D: Allusive Adoption
Has additive manufacturing/3D printing contributed to current business levels?
AFC-Holcroft: “It’s been an ongoing topic, but volumes are still low, which has kept heat treating equipment investments at a minimum.”
Lindberg/MPH: “There have been more requests than in the past few years for sintering applications which, I believe, is largely driven by the increase in 3D metal printing manufacturing.”
Premier Furnace Specialists: “The company has been receiving a number of requests for smaller batch style ovens for the processing of additive manufactured/3D printed materials. We have also fulfilled a number of requests to alter existing or used systems to meet new process requirements.”
SECO/WARWICK: “On the molten metal side, this would be what we call the powdered metals industry, we has not seen much interest in that area this year. One exception is an inquiry that our sister company Retech was fielding.”
Have international supply chain disruptions impacted demand for your company’s equipment?
AFC-Holcroft: “There are certainly disruptions, but we’re finally starting to see some improvements. Our team has worked hard to mitigate the supply chain challenges through unique forward-looking programs with our suppliers and clients. As far as demand goes, it has not had an impact at all. In fact, we are currently experiencing booking levels that we haven’t seen in more than 20 years.”
Can-Eng Furnaces Intl., Ltd.: “Clients are planning ahead to address the longer lead times.”
Lindberg/MPH: “We have noticed that supply chain issues in general, both domestic and international, have created an environment where lead times to build equipment have more than doubled. This has caused many clients to begin looking for alternative solutions to meet their needs, as they cannot wait two-thirds of a year for equipment. The largest delays are with refractory, gas burners, alloy, and many various control components.”
Premier Furnace Specialists: “Actually, we’ve seen an increase in demand for our equipment from various industries impacted by disruptions. Many companies seem to be reassessing their supply chains and expanding production capacity to avoid future disruptions.”
Dual pit furnace and water quench tank system designed and built for a client in the aluminum castings industry. It is used for aluminum solution heat treating of thick walled castings. Each furnace has a 4,000 pound gross load capacity and an operating temperature range of 300°F – 1100°F. (Source: Premier Furnace Specialists/BeaverMatic)
SECO/WARWICK: “Lately our clients are for projects that are further out, 1–2 years in some cases. Most of our end users are aware that prices are still moving up and deliveries are stretched out, however there have been some improvements of deliveries on MCC’s and PLC’s.”
Wisconsin Oven: “Not that we know of.”
The State of Sustainability in Aluminum Market
Has the sustainability push affected demand for your equipment?
Horizontal quench system used for the solution treatment of aluminum parts (Source: Wisconsin Oven)
AFC-Holcroft: “Again, no impact on demand, but our group has been offering many ‘green’ options on our equipment for years to assist our clients in the drive for a reduction in their carbon footprint.”
Can-Eng Furnaces Intl., Ltd.: “Yes, there’s more emphasis on reduced environment impact processes and equipment designs.”
Lindberg/MPH: “Not really. We have had a couple of RFQ[ET7] ’s come in related to green energy, but they are very slow-moving projects with a lot of R&D on the buyers’ end. Additionally, we have been asked to partner with these clients to develop a solution to help them meet the end goal.”
Premier Furnace Specialists: “For a minor segment of clients, the push for sustainability seems to be driving a demand for electrically heated equipment rather than natural gas. Even for those clients, however, the main deciding factors are still local utility costs, existing facility restrictions, and familiarity with existing equipment.”
SECO/WARWICK: “Environmental sustainability has definitely affected what our clients are looking for on most new inquires. Most have strict emissions requirements and are looking for combustion systems with lower NOx and higher fuel efficiency. Peripheral hooding is also commonly requested to capture emissions from around door openings and over charge wells. I would not say that sustainability has diminished the demand, however it has affected what they need with regard to emissions compliance.”
Wisconsin Oven: “Clients occasionally request energy-efficient features and designs, but not more often than in the past.”
Anticipating Growth and Novel Aluminum Applications
What plans are you making to meet future market demand?
AFC-Holcroft: “We are a global group and have recently restructured our organization to better serve our customers. We have also undergone a facility expansion to help reduce our carbon footprint and provide our clients with the best products and deliveries available in the market. This includes an expansion of our build to stock production planning to greatly reduce lead times on UBQ furnaces and EZ endothermic generators among other products.”
Can-Eng Furnaces Intl., Ltd.: “We have increased emphasis on electric battery vehicle component and materials processes and equipment design development. Additionally, we are planning further use of electric energy as an alternate heating source for system designs.”
Lindberg/MPH: “We are looking to work with vendors to create vendor managed inventory in order to reduce lead times, as well as hire additional employees to reduce labor driven lead times. We continually look for additional vendors to remain cost competitive and reducing the overall cost of manufacturing.”
Premier Furnace Specialists : “We’ve expanded vendor and supplier listings. We have also gained experience implementing existing and new alternatives for almost all of our furnace components. By reassessing our standard component choices and offering a variety to clients, we have been able to substantially reduce lead times which allows for more efficient and flexible production while reducing costs.
“We have also added new technology to aid in our manufacturing. Building parts in-house significantly cuts down on lead times and pricing. Thus, clients know that their equipment will have little or no downtime, saving them the time and stress of not running product.”
SECO/WARWICK: “We are adding engineers, field service technicians, etc. and having our “seasoned veterans” bring them up to speed! We have also moved to a larger new office location to accommodate future growth.”
Wisconsin Oven: “We have acquired additional floorspace in recent years and have been hiring aggressively in the last six months.”
Heat Treat Radio host, Doug Glenn, and several otherHeat Treat Today team members sit down with long-time industry expert Dan Herring, The Heat Treat Doctor® of the HERRING GROUP, to finish the conversation about mill processes and production. Enjoy this third informative Lunch & Learn with Heat Treat Today.
Below, you can watch the video, listen to the podcast by clicking on the audio play button, or read an edited transcript.
The following transcript has been edited for your reading enjoyment.
Dan Herring (DH): When it comes to heat treating, the mill will do what we typically call ‘basic operations.’ They will anneal the material and, if you’ll recall, annealing is a softening operation (it does other things, but we will consider it, for the purpose of this discussion, a softening operation) so that the steel you order from the mill will be in a form that you can then manufacture a product from. You can machine it, you can drill it, you can bend it and things of this nature.
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There are various forms and various types of steel that can be ordered directly from the mill. So, the mill typically does annealing operations and normalizing operations. The difference between annealing and normalizing is that annealing has a slower cooling rate than normalizing does.
In the aluminum industry, we don’t talk about normalizing but talk about homogenizing. Homogenizing is to aluminum what normalizing is to steel; it’s a crude analogy, but it’s true. The mill can do other processes; they can do other heat treatments, they can do specialized rolling and things of this nature to give you enhanced mechanical properties. In today’s world, there is a lot of what we call “custom” or “specialty mills” that can manufacture very specialized products. There are mills that primarily make pipe and tube, there are mills that make primarily wire, there are mills that make primarily strip. There are some very customer-specialized mills out there. In general, a mill will produce most of the type of products that we see or use in industry (or the steel for those products), and they will make it in a form that is usable for the end user and heat treated to a condition where the end user can make a product with it. Now, obviously, once you make a product, you may then have to further heat treat that product, for example, to harden it or to give it certain characteristics that you need. We’ll talk about those things in later discussions about this.
What I did want to talk about is the types of steel that are produced by the mills. I’ll do this, hopefully, in a very, very broad context, but I think it will make sense to everybody. Again, metallurgists aren’t known too much for their creativity, so we start out with something called carbon steel. Very original. There is low carbon steel, medium carbon steel and high carbon steel. Low carbon steel has low carbon, medium carbon steel has medium carbon, and a high carbon steel has high carbon.
Now, to be more serious, a low carbon steel typically has less than or equal to 0.3% carbon, or less than 0.3% carbon. A medium carbon steel has between .3% carbon and .6% carbon, and a high carbon steel is greater than .6% carbon. An example of a medium carbon steel might be a 1050 or 1055 grade of steel. Those are commonly used for stampings, for example. So, all of your seatbelt, both the tongue and the receptacle are made of a 1050/1055 steel and they’re austempered to give them both strength and toughness so that in an accident, the buckle won’t shatter because it’s hard but brittle and it won’t bend abnormally and therefore release because it has inherent toughness.
So, there are various things you do with these carbon steels in the heat treat mill to enhance their properties. Carbon steels are used because they’re low cost and they’re produced in tremendous quantities. If you went to a hardware store and bought a piece of steel, it is very likely it will be a simple carbon steel.
On the other hand, we also make alloy steels and, interestingly enough, there are low alloy steels, medium alloy steels, and guess what, high alloy steels. Again, metallurgists are very creative with their names. But idea here is you get higher strength than a carbon steel, a little better wear resistance and toughness, you get a little better corrosion resistance, for example, you might even get some specialized electrical properties and things like this.
But low carbon steel, just to go back to that for a minute, as I said, is produced in huge quantities. Examples are steel for buildings, steel for bridges, steel for ships. We learned our lesson, by the way, with the Titanic; we got the steel right this time. The problem with that steel, by the way, was high in sulfur which embrittled it, interestingly enough, in cold water. So, when it hit the iceberg, the steel shattered because it was brittle because it had too much sulfur. But we learned our lesson.
Titanic, 1912 Source: Wikipedia
There are also various construction materials; anything from a wire that’s used in fencing to automotive bodies to storage tanks to different devices.
When you get into medium carbon steels, because they have a little better strength and a little better wear resistance, you can use them for forgings, you can use them for high strength castings. So, in other words, if you’re producing gears or axles or crank shafts, you might want to consider a medium carbon steel, or seatbelt components as we talked about.
Then there is the family of high carbon steels. Again, they can be heat treated to give you extremely high hardness and strength. Now, they’re obviously more expensive than medium carbon or low carbon steels, but when you’re making knives and cutlery components, (knives and scissors, for example), when you’re making springs, when you’re making tools and dyes. Railroad wheels are another example of something that might be made out of a high carbon steel. As a result of this, the type of product that your company is producing, means that you’re going to order a certain type of steel that you can use to make your product and give it the longevity or the life that your customers are expecting.
One of the things about steel that differentiates it from aluminum: Aluminum has a very good strength to weight ratio. But so again does steel, but obviously the strength to weight ratio, the weight is specifically much more, from that standpoint. But we can take steels that we produce from the mill, and we can do processes like quench and temper them. If we do that, we can make things like pressure vessels, we can make the bodies of submarines, for example, we can make various pressurized containers and things.
Stainless steel pots Source-Justus Menke at Unsplash.com
There are a lot of different things we can do with steels to enhance the products that we’re producing. Besides just low carbon steel or carbon steels and alloy steels, we then can go into the family of stainless steels, for example. Most people think of stainless steels as being corrosion resistant. I’ll warn you that not all stainless steels, however, are corrosion resistant; some of them can corrode in certain medias or chemicals, if you will. But with stainless steels, a good example of that is food processing containers or piping or things that will hold food or food products, and again, we can make with stainless steels a variety of different products. We can make different components for buildings, for example, or for trim components and things.
Besides stainless steels, of course, we can make tool steels. Now, tool steels represents a very, very high alloy steel. The alloying content of tool steels is typically 30 to maybe 50% alloying elements: molybdenum and vanadium and chromium and these types of materials. As a result, we can make a lot of dyes and we can make a lot of cutting tools, we can make taps and other devices that are used to machine other metals, if you will. So, tool steels have a lot of application.
But there are a lot of specialty steels that are made by the mills, as well. One example of that, that I like to talk about or think about, is spring steels because you can make various things like knives and scraper blades, putty knives, for example, besides cutlery knives. You can make reeds for musical instruments, the vibrating instruments in the orchestra, if you will. You can make springs and you can make tape measures, tapes and rules and things of this nature out of these various spring steels, if you will.
Depending on what your end-use application is, the bottom line here is that whatever your end-use application is, there is a particular type of steel that you should be using and there is a form of that steel that you can use. Again, those steels can be produced by a variety of different processes; they can be forged, they can be rolled, hot and cold rolled, again. And when I’m talking about hot rolling, I’m talking about temperatures in typically the 1800-degree Fahrenheit to 2200/2300-degree Fahrenheit range. When I talk about hot rolling, the metal is, indeed, hot, if you will.
By the way, roughly, iron will melt at around 2800 degrees Fahrenheit, just to give you a perspective on that, if you will.
The key to all this is that the form that is produced by the mill meets the needs of their customers and their customers’ applications. If you need a plate, for example, they will produce plate in various sizes and thicknesses.
Rolling direction Source: Barnshaws Group
By the way, just a quick note, and this is for all the heat treaters out there: Be careful of the rolling direction in which the plate was produced. We have found that if you stamp or cut component parts out of a plate with the rolling direction, or transverse or across the rolling direction, you can get vastly different properties out of the products. It’s amazing that you can get tremendous distortion differences from heat treated products depending on the rolling direction. If you’re stamping or forming out of a plate, you’re transverse or in line with the rolling direction. Most people don’t even think of that. They take the plate, they move it into the stamping machine, and they could care less about the rolling direction. Then, when the poor heat treater does his heat treating and distorts all the parts, the man comes back and says, “What’s wrong?”
By the way, that little example took only nine years of my life to solve. We had some, what are called, "springs" that are the backing on a knife. When you open a knife blade, there is a member that it’s attached to called a spring. Those springs were distorting horribly after being oil-quenched in an interval quench furnace. It happened to be a conversation around the coffee machine where one of the guys made the comment that, “You know, it’s really funny, we never had problems with distortion until we got that new stamping machine in.” Low and behold, in investigating it, the old machine took the plate in one direction, the new machine had to take the plate in a different direction and it rotated. . . . End result.
So, I guess for everybody listening, the key to this is that no matter what the material is that’s being produced, we need to use it sometimes in its cast form, we need to use it sometimes in its finished forms, which again can be bar and sheet and plate and wire and tube and things of this nature. And to get those shapes, we need to do things like hot and cold rolling, we need to do forging, we need to do operations like piercing to actually produce rings and things of this nature. So, although I didn’t go all the details about that, there is a lot of information out there about it. I wanted to set the stage for it to say that it’s the end-use application by the customer that fuels the type of steel being produced and fuels the form in which the steel is produced.
Perhaps as a last comment, on my end anyway, at this point, is the fact that a mill is a business just like anyone else’s business. We’re always looking for ways to cut costs, (not cut corners, but reduce cost), and mills have found that in the old days — and the old days weren’t necessarily the “good old days” — a mill made everything; they made all types of steel, they made all types of shapes and forms. But today, a lot of mills are saying it’s not economical to produce that particular type of steel or that particular form of steel, so we’ll leave that steel production to someone else, and we’ll only concentrate on high volume production.
You know, it’s very producing steel, a typical heated steel (and people will probably correct me on this), is somewhere in the order to 330,000 pounds of steel. So, if you’re a small manufacturer and don’t happen to need 330,000 pounds of steel, you have to go to a distributor and, more or less, maybe compromise a little bit to get the steel that you need. But the mills are producing large quantities of steel and very specialty steel grades, in general, today.
Doug Glenn (DG): It’s essentially specialization of labor so it helps keep each individual mill’s cost down, but it doesn’t have the variety it used to.
Let’s open up for questions, really quick. I’ve got one if nobody has one, but I hope somebody else has one. So, fire away if you’ve got one.
Carbon steel gate valve Source: Matmatch
Bethany Leone (BL): When you said that, Doug, my question jumped out of my head. I had 3 questions though but the ones I remember aren’t that important. One is — I recently visited an old blast furnace in Pittsburgh, Carrie Blast Furnaces; everybody should go, if you’re in the Pittsburgh area), so some of this sounds familiar. The second thing I was wondering is just how high can the carbon percentages go in carbon steels, .6%+, right?
DH: Yes, greater than .6%, and it’s not uncommon for carbon in various types of steels to go over 1%. It typically can go in certain tool steels and things higher than that. But one of the things that differentiates a steel from a cast iron is the percentage of carbon in the material. And carbon over 2% is considered a cast iron as opposed to a steel. Steel has a carbon percentage from .008 all the way up to 2%. That’s a great question and something to be aware of. When you buy a cast iron skillet, for example, you’re getting a material that has greater than 2% carbon in it.
BL: The other question I had is sort of more on the business end, if you know any of this, is- with the high energy that it takes to process iron, I imagine there have been efforts to try to reduce costs to produce energy that’s used to be a technology and innovation and especially right now with many people concerned with sustainability in those practices, are there ways that maybe even clients have influenced how businesses iron manufacturers in the iron manufacturing world have been trying to keep those environmental loads down, do you know?
DH: That’s a very intriguing question. I don’t have all the facts and information on it, but I’ll share a few things. As opposed to the production of aluminum, which is primarily using electricity, steel production uses typically natural gas. There were, in the old days, oil-fired equipment and things of this nature but today it’s typically gas-fired furnaces and things of this nature. Now, I have to be careful when I say that because some of the steel refining methods, (for example, the vacuum arc remelting furnaces and things of this nature), again, use carbon electrodes and use electricity, if you will, in the process. But essentially, what they’re trying to do is they’re trying to, for example, capture waste heat and reuse it to preheat different materials and processes and things of this nature, and they’re using methods that are trying to make the overall equipment more energy-friendly; if you will, better insulations, better fit of components than the old days when they didn’t care too much about if we got heat pouring out into the shop, we don’t care. Today, we really care about those things.
But steelmaking, again — for a different reason than aluminum — is a very energy intensive process; it uses a lot of energy to produce steel.
I’ll make a quick comment also, and I’m not saying this especially from anyone internationally who happens to be listening in to this: I’m not saying this is an “America only” comment, if you will, but in 1900, the largest industry, the largest company in the U.S. was U.S. Steel. United States Steel was the number one most profitable company in the country. If you think about it, throughout what would be the 20th century, steel and steel production has fueled, if you will, the American economy. We’ve since transitioned to other more angelic materials, if I can use that phrase; I won’t define it. However, who do you think produces over 50% of the world’s steel today? Anyone want to guess?
DG: The U.S.?
DH: No! China. And where is the manufacturing growth taking place? So, the production of aluminum, the production of steel, fuels manufacturing is my message here.
Yes, there are environmental consequences, but I often use the phrase and, again, this is not intended to be insultive to any one country, but for all the recycling, for all the energy saving, for all the environmental progress we can make in the United States, if we could reduce coal consumption in China (and India, of course), it would have major, major impact on the environment. And that’s not having 100-year-old steel mills, like we have here in the U.S., will go a long way, if you will.
DG: I’m going to give you 30 seconds, Dan, to answer one more question, okay? Here’s the question: Aluminum doesn’t rust, most steels do. Why is that?
DH: In simple terms, because aluminum reforms an aluminum oxide on the surface and that oxide is impenetrable, virtually, to further oxidation, whereas iron produces an iron oxide on the surface in the form of rust, it flakes off and you can reoxidize the surface. Now, there are steels — core10 is an example — self-rusting steels, that once they rust, they don’t reoxidize, but that’s the basic difference, Doug, between them.
DG: Perfect, perfect.
Alright guys. Thank you very much, Dan. I appreciate it. We’re going to get you on deck for another one here pretty soon on another topic, but we appreciate your expertise.
DH: Always a pleasure and, as I’ve said, I’ve reduced 3,000 pages into 30 minutes so hopefully people that are interested will read up more on these processes.
Al-u-MI-ni-um. A-LU-mi-num. Heat treating aluminum is not something we often get a chance to talk about, but it is everywhere. From the bikes we ride to the foil bound around last night's burger, this light-weight metal certainly has a place in our daily life. Today's Technical Tuesday original content article highlights some of our favorite aluminum processing features over the years.
Aluminium is the most widely available lightweight bike frame material, up to three times lighter than steel frames. It provides the low weight, stiff, durable, rust resistance, and affordable ride that we look to enjoy up mountains, through city roads, and along park trails. But aluminum also has a bunch of other uses, as in the medical and automotive industries. How is this lightweight metal heat treated? Let's review these three content pieces from Heat TreatToday'sfiles.
Combatting Corundum
Taking it a step back to aluminum melting and refractory, hear what Dan Szynal, VP of Engineering & Technical Services at Plibrico, has to share about the causes and mediation of corundum growth.
What better way to learn about aluminum processing and heat treat rather than watching it happen in this 1940s-1950s video? It's got the classic black & white, intense masculine voice narrator, and the illustrated graphics everyone loves. What do you think of this 22 minute video? Let us know!
"When fully developed and implemented," this piece of news reads, "it will eliminate direct greenhouse gas emissions from the smelting process and strengthen the closely integrated Canada-United States aluminum and manufacturing industry." Learn more about this innovative process for aluminum processing and then compare with current greenhouse advances in the steel industry.
When you are a new heat treater, there are really only three things you want to know to get your bearings: What is it? How does it work? Why does it matter? That's it. What does that mean when we discuss "VAB"?
This best of the web article walks you through the three questions mentioned above, several advantages of vacuum aluminum brazing, and heating control.
An excerpt:
"The dwell time (soak) at braze temperature must be minimized as melted filler metal is vaporizing in the low pressure (high vacuum) environment. Too much filler metal vaporization can result in poor joint wetting and subsequent loss of joint strength and sealing ability. After the final brazing soak is complete, a vacuum cooling cycle follows, which stops material vaporization and solidifies the filler metal."
Jim Grann, Technical Director, Ipsen (photo source: www.ipsenharold.com)
We all like to make savvy commercial decisions, in fact, Heat Treat Today’s 101 Heat Treat Tips on page 20 of this digital magazine is a great example of tips that can save you time and money. But will it pay off to use your conventional vacuum furnace for aluminum brazing?
Questions involving safety, effectiveness, and quality might come to mind with this proposal. Before implementing such a strategy, head over to Heat Treat Today’s best of the web Technical Tuesday article by Jim Grann, technical director at Ipsen. He tackles the components of aluminum brazing versus the capabilities of conventional vacuum furnace as well as detailing some of risks that can happen if you do try to use your conventional vacuum furnace for aluminum brazing.
An excerpt: “By nature, vapor pressure aids in the depletion of magnesium and parent aluminum alloys in high vacuum, depositing magnesium onto the hot zone and into the shielding… Proper vacuum aluminum brazing requires special components that standard vacuum furnaces generally do not have, including…”
A global technology group, an industrial gases company, an additive and design company, and an engineering university in Germany have entered into a research partnership with the end goal of supporting the aerospace and automotive industries through their research and development of aluminum based-alloys.
Oerlikon, a global technology group, entered into a research partnership with Linde, an industrial gases company, GE Additive, an additive and design company, and the Technical University of Munich (TUM), a leading German university in engineering, to conduct additive manufacturing (AM) research with the aim of developing new high-strength, lightweight aluminum-based alloys that can serve the safety and weight reduction needs of the aerospace and automotive industries.
Dr. Marcus Giglmaier, Project Manager for the AM Institute
This collaboration seeks to address the challenge of aluminum AM. “There are significant challenges during the AM of aluminum alloys because the temperatures reached in the melt pool create an extreme environment that leads to evaporation losses of alloying elements that have comparatively low boiling temperatures — such as magnesium,” said Dr. Marcus Giglmaier, project manager for the Additive Manufacturing Institute and research funding manager. “Additionally, the cooling rates of more than 1 million °C per second, create high stresses during the solidification process, which can cause micro cracks in the solid material.”
The project draws on the strengths of each of its members. Oerlikon’s experience in powder and material science will contribute to the development of the novel material; Linde’s technology and expertise in gas atmosphere control and evaporation suppression during the AM process – including the processing of aluminum-based alloys – overcomes impurities within the print chamber, which will help manufacturers achieve optimal 3D-printing conditions; GE Additive will assist in the collaboration; and, for its part, the Institute of Aerodynamics and Fluid Mechanics (AER) at TUM will be able to provide a detailed understanding of the physical phenomena taking place during the AM process using numerical simulations.
From left to right: Dr Sven Hicken (Business Unit Head, Oerlikon AM), Prof Thomas Hofmann (President, TUM), Jason Oliver (President and CEO, GE Additive), Dr Wolfgang Dierker (CEO, GE Germany), Dr Christoph Laumen (Executive Director R&D, Linde AG), Prof Michael Suess (Chairman of the Board of Directors, Oerlikon Group), Dr Christian Haecker (Head of Industrialisation, Oerlikon AM), Dr Andreas Lessmann (Managing Director, GE Additive Germany GmbH, Senior Leader, Legal Operations), Dr Christian Bruch (Executive Vice President & CEO, Linde Engineering), Andreas Rohregger (Head of Global Properties, GE Additive), Dr Alice Beck (Deputy Director, TUM ForTe) (Courtesy Oerlikon)
An aluminum alloy developed and patented five years ago has been identified as one of the strongest aluminum additive manufacturing powders commercially available.
Mike Bond, Director of Advanced Material Technology at Aeromet
Aeromet’s A20X™ surpassed the key 500 MPa UTS mark following a recent research project involving aero-engine giant Rolls-Royce and additive manufacturing equipment specialist Renishaw. Heat-treated parts produced using A20X™ Powder have achieved an Ultimate Tensile Strength (UTS) of 511 MPa, a Yield Strength of 440 MPa and Elongation of 13%. Crucially, parts additively manufactured with A20X™ Powder maintain high-strength and fatigue properties even at elevated temperatures, outperforming other leading aluminum powders.
“Since bringing the A20X™ alloy to market for additive manufacturing 5 years ago we have seen significant adoption for high-strength, design-critical applications,” said Mike Bond, Director of Advanced Material Technology at Aeromet. “By working with Rolls-Royce, Renishaw, and PSI, we have optimized processing parameters that led to record-breaking results, opening up new design possibilities for aerospace and advanced engineering applications.”
The HighSAP project was backed by the UK’s National Aerospace Technology Exploitation Programme (NATEP). A20X™ Powder for additive manufacturing is derived from the MMPDS-approved A20X™ Casting alloy, the world’s strongest aluminum casting alloy, which is in use by a global network of leading aerospace casting suppliers.