In today’s Technical Tuesday installment, we highlight the various techniques and developments in the world of metal AM as it pertains to post-process heat treating. Check out the trivia quiz below to test your knowledge of the AM/3D industry, the processes, and the technology.
Additive manufacturing (AM), commonly known as 3D printing, has a history marked by constant innovation for uses across the space, aerospace, medical, food, and manufacturing industries, to name a few. While AM is known to support, streamline, and customize part production, advanced materials paired with evolving AM techniques are creating new possibilities in materials engineering and industrial manufacturing. Due to the nature of this ever-developing technology, in-house heat treaters must continually learn about AM components and how thermal processing may enhance component properties.
Emanuel “Ely” Sachs
What was the original name for additive manufacturing (AM), circa 1980s? A) 3D printing B) Rapid prototyping (RP) C) Additive manufacturing (AM) D) Rapid tooling (RT)
What grade of stainless steel is most commonly used for AM to achieve varying levels of strength, hardness, and elongation when heat treated? A) 17-4 PH B) 316L C) 304 D) 430
Who is Emanuel “Ely” M. Sachs? A) An engineer at GE Aviation who combined multiple parts into one huge, complex design using a laser-based additive manufacturing method called direct metal laser melting B) An engineer at Stratasys Ltd., an American-Israeli manufacturer that began using a material extrusion based process with their FFF (fused filament fabrication) technology to print parts, patented in 1989 C) A professor of Mechanical and Materials Engineering at Worchester Polytechnic Institute who evaluated the post process heat treating of DMLS titanium alloy parts D) An MIT engineering professor who patented the process of metal binder jetting technique in 1993
What do cast parts made from powder metallurgy methods and AM parts have in common? A) The same heat treatment cycles produce the best results B) Custom cycles are used in less than 2% of both applications C) Parts exhibit porosity D) None of the above
What are the most commonly adjusted parameters to achieve higher yield strength when heat treating AM parts? A) Cooling and heating rate B) Temperature and time C) Time and pressure D) Temperature and pressure
Why is HIP known as the “gold standard” for processing AM parts for space? A) Eliminates porous microstructures without compromising the part’s geometries and dimensions B) High level of control and uniformity C) Combines high temperature and pressure to improve a part’s mechanical properties D) All of the above
What is NOT a potential benefit of additive manufacturing? A) Immediate cost savings B) Fast part production C) Rapid prototyping D) Opportunity for increased automation and use of robotics
What are the two main categories for most 3D printing methods? A) Those that use liquid binding polymers, and those that don’t B) Binder jetting technology (a non-melt-based process) and melt-based processes C) Both A and B D) Neither A nor B
Which alloy was originally developed for aerospace applications but became one of the most common biomedical alloys? A) Inconel 718 B) Inconel 625 C) Ti-6Al-4V D) Hastelloy C22
What was the first rapid prototyping method to produce metal parts in a single process (and is one of the most widely used AM technologies to manufacture Ti-6Al-4V parts)? A) Powder-bed fusion (PBF) B) Directed energy deposition (DED) C) Sheet lamination (SL) D) Direct metal laser sintering (DMLS)
In what way does high temperature processing — specifically HIP below the annealing temperature (1470°F/799°C) — improve DMLS Ti-6Al-4V parts? A) Preserves surface roughness and enhances osteointegration B) Reduces porosity and enhances corrosion resistance C) Both A and B D) Neither A nor B
What is the ideal way to process 3D printed parts made using liquid binder polymers? A) Print the parts in-house followed by debind and sinter. B) Have AM parts delivered in-house for heat treating when parts are at the “Green” stage C) Have AM parts delivered in-house for heat treating when parts are at the “Brown” stage D) None of the above
Industry experts agree: 2025 is a year of significant, high-tech developments. In this Technical Tuesday, hear from three heat treat industry consultants on current and incoming technological advances, from miniaturization and customization to artificial intelligence.
Michael Mouilleseaux, general manager at Erie Steel, Ltd, opens the discussion by asking what role AI has in a perfect world of heat treating; Thomas Wingens, president of Wingens Consultants, predicts six major technologies to look for in 2025; and Dan Herring, a.k.a. The Heat Treat Doctor® and owner of The HERRING GROUP, Inc., points out how the trend toward smaller is affecting the heat treat industry.
This informative piece was first released inHeat Treat Today’sJanuary 2025 Technologies To Watch in Heat Treating print edition.
AI’s Place in Heat Treating?
by Michael Mouilleseaux
The benefits of AI are purported to be the ability to reduce the time required to complete complex tasks, such as data analysis, while reducing human error and providing both unbiased decision making and data-driven system enhancements … and by the way, it can operate 24/7 without breaks!
Does AI have a place in heat treating?
Here’s what I would want my heat treat AI (HT AI) to be able to do with a gas-fired atmosphere furnace.
Combustion System:
My HT AI will continuously monitor the free oxygen of all the burners and keep them at a perfect ratio, thereby optimizing performance and gas consumption. It will track these changes and provide analysis of any trends that it “perceives,” so to speak.
My HT AI will continuously monitor combustion air pressure and message me in time to have the air filters changed before it affects performance. It will track this and provide historical and prescriptive information.
My HT AI will periodically perform a “tube check,” whereby it will shut off combustion in a tube and monitor the free oxygen, recognizing that any diminishment from “atmospheric” O2 levels indicate the potential of a tube leak. It will track this and provide analysis of any trends that it perceives.
My HT AI will track when system thermal stasis is achieved, monitor gas consumption for each discrete heat treat cycle, provide analysis of trends that it perceives, and recommend thermal cycle changes to optimize these cycles.
My HT AI will facilitate the optimization of the critical human assets in process engineering, product quality and equipment maintenance.”
Michael Mouilleseaux
Atmosphere Control System:
My HT AI will continuously monitor the atmosphere flows required to achieve the requirements for each heat treat cycle. It will track “atmosphere recovery” and provide analysis of any trends that it perceives (i.e., increased usage as a precursor to a furnace leak).
My HT AI will periodically perform a furnace check, whereby it compares the composition of the Endo gas in the furnace to that exiting the generator, providing a measure of furnace integrity. It will track this and provide analysis of any trends that it perceives.
My HT AI will confirm “tube check” data (see above) with atmosphere usage to evaluate its potential effects on process integrity and make actionable recommendations. It will track these incidents and provide analysis of any trends that it perceives.
My HT AI will provide assurance of system performance and actionable information.
Shoot for the Moon:
My HT AI will have the unique ability to integrate metallurgical results with process information and thereby provide the ability to optimize the heat treating process AND metallurgical results.
My HT AI will allow me to input material chemical and hardenability data and, by comparing actual results with the calculated, or prospective results, provide confirmation of the thermal and quenching segments of the process.
My HT AI will be able to correlate IGO results with furnace integrity checks (i.e., leaks) and over time establish hard limits for allowable leak rates.
My HT AI will be able to correlate actual retained austenite levels in carburized case with furnace carbon potential and make data-driven process modifications to optimize this.
My HT AI will be able to correlate the shape of the case depth curve with the carburizing cycle and the material type, and it will make data-driven process modifications to optimize this.
My HT AI will have the ability to develop new heat treat thermal cycles specific to my furnaces extrapolated from existing data.
My HT AI will provide a level of system performance heretofore not achieved, that not only assures adherence to established standards but provides a clear path of continuous improvement via data analysis and actionable actions. Product results will be validated by total process control, and total process control will assure attainment of product results.
My HT AI will facilitate the optimization of the critical human assets in process engineering, product quality and equipment maintenance.
In short, my HT AI will afford the heat treating community the ability to finally jettison the mantle of “black art” and join the community of high-tech engineered processes.
About the Author:
Michael Mouilleseaux General Manager Erie Steel, Ltd
Michael Mouilleseaux has been at Erie Steel in Toledo, OH, since 2006 with previous metallurgical experience at New Process Gear in Syracuse, NY, and as the director of Technology in Marketing at FPM Heat Treating LLC in Elk Grove, IL. Having graduated from the University of Michigan with a degree in Metallurgical Engineering, Michael has proved his expertise in the field of heat treat, co-presenting at the 2019 Heat Treat show and currently serving on the Board of Trustees at the Metal Treating Institute.
2025 will be the year of invention and application. There are six major technologies to be looking out for: AI management software, giga casting for the EV industry, high-pressure quench furnaces, thermal processing specialty materials, processing for steel enrichment, and practices for cleaning consistency.
AI Management Software
Some new heat treat shop management software is now available. It utilizes artificial intelligence to save labor while documenting all processes in real time. The software easily adapts to the way we work and is much easier to learn and implement than the software of the past. I see this as the number one investment item for commercial heat treaters in 2025, as it is the cheapest and easiest way to automate with a great ROI while increasing quality and customer service.
Giga Casting
With Tesla as the main driver, very large so-called “GIGA” H13 aluminum dies of 3 to 8-ton weight have really taken off in the last years, in particular for new electric car models, and the demand for very high pressure quench furnaces is increasing in the U.S. (more to come in a later article).
Vacuum Oil Quenching
However, even with the most advanced designs and high-pressure efforts, gas quenching with nitrogen has its limits, and the use of helium is not considered anymore because of its immense cost, even with a recycling system in place. Vacuum oil quenching has become a viable alternative in recent years not only in combination with LPC (low-pressure carburizing) but also with the use of materials like AISI 52100 that would be typically heat treated in atmosphere integral quench furnaces but show lesser distortion with the variation of pressures over the oil bath, which can shift the oil boiling phase peak to lower temperatures (e.g., from 650°C (1200°F) at atmospheric pressure to 400°C (750°F) at 1 mbar pressure). Some new modern vacuum oil quench furnace designs have recently entered the market, showing excellent surface cleanliness and distortion results. Aside from the better quality, they offer a much safer, cleaner and more pleasant work environment.
Specialty Materials
In general, we see a higher demand for the thermal processing of specialty materials; for example this is seen with the hydrogen decrepitation of titanium, tantalum, niobium, or rare earth element materials, powder processing or sinter processes, and surface diffusion processes.
Steel Enrichment
Enriching stainless steel with nitrogen is not new, but it is gaining momentum and more applications. One method for\ low-temperature processes on austenitic stainless steels around 370°C (690°F) is called S-phase case hardening, and the high temperature version around 1100°C (2010°F) is called solution nitriding. Both processes were initially established in the early 90s in Europe but seem to be gaining momentum and more comprehensive applications worldwide over the last years.
Figure 1. For 2025, “We see more fully enclosed vacuum solvent cleaning in heat treat shops to ensure a higher standard and consistency of the surface cleaning results compared to the fading of water cleaners.” – Thomas Wingens, WINGENS CONSULTANTS
Cleaning Consistency
Speaking of surface processes: The cleaning of components has been a thankless process, especially in commercial heat treatment, as it is seen as a necessity that is not necessarily paid for by the clients but is necessary to have uniform dissociation on the surface of a part to ensure a uniform case (e.g., nitriding case). There are well-defined standards for temperature uniformity and hardness testing, but cleaning consistency needs to be addressed, as it can be very impactful. We see more fully enclosed vacuum solvent cleaning in heat treat shops to ensure a higher standard and consistency of the surface cleaning results compared to the fading of water cleaners.
About the Author:
Thomas Wingens President WINGENS CONSULTANTS
Thomas Wingens has been an independent consultant to the heat treat industry for nearly 15 years and has been involved in the heat treat industry for over 35 years. Throughout his career, he has held various positions, including business developer, management, and executive roles for companies in Europe and the United States, including Bodycote, Ipsen, SECO/WARWICK, Tenova, and IHI-Group.
Everywhere we turn today, the products we use are getting smaller, more compact and more powerful. This is true across all industries, from aerospace to automotive, from medical to electronics, and from energy to semiconductors to name a few. Today, miniaturization, portability and customization have become major design objectives for almost all manufacturing segments.
These trends are irreversible and are, or will be, found even in the most unlikely of places — both in mining of resources taking place deep under the ocean floor and eventually on other planets. The key question then becomes, how will all of this influence our heat treating operations?
Miniaturization, Portability and Customization Today
Given the ever-increasing demand for higher performance in a smaller footprint, we have often focused our energies on taking existing products and adapting them for use. But in the long term, this is not sustainable. For example, not only is gear noise reduction critical in our submarines, but the medical and robotics markets are continuously searching for smaller, more efficient, more application specific and more intelligent drive systems and motors with increased torque density.
Heat treatment will experience a metamorphosis and emerge more broadly as thermal treatment. The age of metals as we have known it has become the age of materials: ceramics, composites, powder materials, glasses, polymers, fiber-reinforced plastics, and even nanomaterials.
Dan Herring, The Heat Treat Doctor®
Another example, although not new, is miniaturization in vehicle electronics, especially as it relates to data collection where demand is high for smaller, more powerful and, yes, cheaper components. Integration into the electronic control units via on-board power systems has seen the need for more cables in vehicles and positioning connectors, which means more contacts/connections on the electronic components without significantly increasing the installation space.
Similarly, there is a huge demand for portability. This is true not only in our electronics (just think about how cell phones or computers have changed over the last ten years), but there is a growing need for portable medical devices so that medical care can be brought to the patient rather than the other way around. For example, longer battery life and lighter weight are critical for devices such as portable oxygen concentrators.
What Does This Mean for the Heat Treatment Industry?
Looking ahead, we will see both short and long-term changes to our industry. Happening today and continuing in the near term, heat treaters are working closer than ever with design and manufacturing engineers as they focus on products that reduce environmental impact, are produced at lower unit cost, and with improved part quality. Still, the era of mass recalls must come to an end. And the cost of heat treating is less than it was even a decade ago. But as manufacturing demand evolves due to consumer expectation, process and equipment flexibility will become keys to meeting the highest quality standards in an on-demand world.
Historically, changes in the heat treat industry has been evolutionary and incremental in both nature and effect. There have been notable exceptions such as the invention of the oxygen probe or low pressure vacuum carburizing. But to meet the manufacturing demands of the future, change will need to be more revolutionary and abrupt in nature, a game changer.
Given the ever-increasing demand for higher performance in a smaller footprint, we have often focused our energies on taking existing products and adapting them for use. But in the long term, this is not sustainable. For example, not only is gear noise reduction critical in our submarines, but the medical and robotics markets are continuously searching for smaller, more efficient, more application specific and more-intelligent drive systems and motors with increased torque density.
Dan Herring, The HERRING GROUP, Inc.
Heat treatment will experience a metamorphosis and emerge more broadly as thermal treatment. The age of metals as we have known it has become the age of materials: ceramics, composites, powder materials, glasses, polymers, fiber-reinforced plastics, and even nanomaterials. As a result, we will find ourselves needing, for example, to expand our heat treat capability and equipment to deal with such items as process temperature ranges from -200°C to 1850°C (-330°F to 3360°F) or greater or at pressure/vacuum levels heretofore only achievable in laboratories or specialty applications.
As product sizes decrease, load sizes will become smaller out of necessity. And as a result, our heat treat equipment must be small lot capable with tighter controls to achieve higher quality along with tremendous process flexibility.
Final Thoughts
History’s enduring legacy is that change is inevitable. Just think back to how the heat treatment industry has evolved, from the campfire to the blacksmith to the modern heat treater, from the artisan to the era of mass production, from the art of heat treating to the science of heat treatment. The lesson is that to adapt, one must constantly innovate and invent. Miniaturization, portability and customization in whatever form they take are here to stay. Perhaps even teleportation (the ultimate miniaturization?) isn’t that far off after all, considering flight was unheard of a little over a century ago.
About the Author:
Dan Herring (The Heat Treat Doctor®) The HERRING GROUP, Inc.
Dan Herring has been in the industry for over 50 years and has gained vast experience in fields that include materials science, engineering, metallurgy, new product research, and many other areas. He is the author of six books and over 700 technical articles.
The Heat Treat Doctor® has returned to offer sage advice to Heat Treat Today readers and to answer your questions about heat treating, brazing, sintering, and other types of thermal treatments as well as questions on metallurgy, equipment, and process-related issues.
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Clients often want to know or specify that their component part surfaces are “bright” or “shiny” or “clean.” Other times they desire to have a surface condition that is “scale free” or “oxide free” after heat treatment. But how, if at all, can we quantify what these terms mean? Let’s learn more.
“Shiny” and “bright” are words that are highly subjective. This is often a source of confusion not only for the heat treater, but the manufacturer and, in some cases, even the end user of the products. Heretofore, the answer depended on one human being’s interpretation as opposed to another, and evaluations depend not only on the type of material but also the mill practices used, manufacturing methods employed, heat treatment processes, and the level and type of contamination introduced before and after processing.
Traditional Approach
Figure 1. Temper color chart atmosphere or tempering in air or an “inert” gas such as nitrogen. Source: Abbott Furnace Company
Traditionally, we have relied on color charts (Figure 1) to tell the approximate temperature at which discoloration took place, that is, an oxide formed on the (steel, stainless steel, or tool steel) surface of a component part. This method is still in use today when cooling parts in a furnace
As mentioned, the perception and interpretation of color is different for different people. Lighting (natural light or plant illumination), the environment in which one views color, eye fatigue, the age of the observer, and a host of other factors influences color perception. But even without such physical considerations, each of us interprets color based on personal perception. Each person also verbally describes an object’s color differently. As a result, objectively communicating a particular color to another person without using some type of standard is difficult.
There also must be a way to compare one color to the next with accuracy.
New Approach
Today, portable spectrophotometers (Figure 2) are available to measure color and help quantify brightness measurements. These types of devices are designed to meet various industry standards including:
In simplest terms, a spectrophotometer is a color measurement device used to capture and evaluate color. Every object has its own reflectance, or the amount of light it reflects, and transmittance, or the amount of light it absorbs. A reflectance spectrophotometer shines a beam of light and measures the amount of light reflected from different wavelengths of the visible spectrum, while a transmission spectrophotometer measures how much light passes through the sample. Spectrophotometers can measure and provide quantitative analysis for just about anything, including solids, liquids, plastics, paper, metal, fabric, and even painted samples to verify color and consistency.
Spectrophotometers provide the solution to the subjective problem of interpreting the color of the surface of a component part that has been heat treated, brazed, or sintered because they explicitly identify the colors being measured; that is, the instrument differentiates one color from another and assigns each a numeric value.
As an example, the brightness of steel tubes annealed in a rich Exothermic gas atmosphere was measured against tubes that had not been processed (Figure 3). Having this definite measurement of the surface changes allowed the heat treater to provide their client with a definitive statement on the change after processing.
CIE Color Systems
The Commission Internationale de l’Eclairage (CIE) is an organization responsible for international recommendations for photometry and colorimetry. The CIE standardized color order systems include specifying the light source (illumination), the observer, and the methodology used to derive values for describing color, regardless of industry or use case.
Though spectrophotometers are the most common, for some applications colorimeters can also be used, but these are in general less accurate and less suitable for a heat treat environment.
There are three primary types of spectrophotometers on the market today used for print, packaging, and industrial applications: traditional 0°/45° (or 45°/0°) spectrophotometers, primarily used for the print industry; sphere (or diffuse/8°) spectrophotometers, primarily used in the packaging industry; and multi-angle (MA) spectrophotometers, for use in industrial environments. These instruments capture color information, and in some cases can capture appearance data (e.g., gloss).
Multi-angle (MA) spectrophotometers are best suited for measurements involving special surface effects, such as those found on metal surfaces and coatings and include those with surface contaminants and even can quantify cosmetic appearance. These are typically used on the shop floor, in the lab and in quality control, and even can be found in shipping areas.
MA spectrophotometers require users to verify five or more sets of L*a*b values or delta these terms). They typically have an aperture size of 12 mm, which is too large for measuring the fine detail that occurs in many small-scale industrial applications. Primary illumination is provided at a 45° angle. Some models have secondary illumination at a 15° angle.
Figure 3. Example of a product test — color and oxidation level test. Source: X-RIte
An application example for an MA spec trophotometer lies in their use for collecting colorimetric data on special effects coatings in the automotive industry, capturing reliable color data in cases where special effect coatings are used.
Final Thoughts
In this writer’s opinion, a spectrophotometer should be in every heat treat shop! You will be doing both yourself and your customers a valuable service and take the guesswork out of one of the most commonly asked questions – is it bright?
References
Herring, Dan H. Atmosphere Heat Treatment Volume 1. BNP Media, 2014.
X-Rite Pantone. “A Guide to Understanding Color.” Accessed October 10, 2024. https://www.xrite.com/learning-color-education/whitepapers/a-guide-to-understanding-color.
X-Rite Panatone. “Tolerancing Part 3: Color Space vs. Color Tolerance.” Accessed October 10, 2024. https://www.xrite.com/blog/tolerancingpart-3.
X-Rite Pantone. “X-Rite Portable Multi Angle Spectrophotometers.” Accessed October 10, 2024. https://www.xrite.com/categories/portable-pectrophotometers/ma-family.
About the Author
Dan Herring “The Heat Treat Doctor” The HERRING GROUP, Inc.
Dan Herring has been in the industry for over 50 years and has gained vast experience in fields that include materials science, engineering, metallurgy, new product research, and many other areas. He is the author of six books and over 700 technical articles.
How well do you know the “anatomy” of your key heat treat equipment? In this “Anatomy of . . .” series, industry experts indicate the main features of a specific heat treat system. In this installment, the full-page spread identifies main features of a front-loading vacuum furnace.
The mark-ups for these reference images are provided by Jim Grann, technical director, Ipsen.
View the full graphics by clicking the image below.
This Technical Tuesday article is drawn from Heat Treat Today’sNovember 2024 Vacuumprint edition with a special focus on vacuum furnace technologies.
Search www.heattreatbuyersguide.com for a list of vacuum furnace providers to the North American market. If you are a vacuum furnace supplier and are not listed here, please let us know at editor@heattreattoday.com.
This series will continue in subsequent editions of Heat Treat Today’sprint publications. Stay tuned!
Find Heat Treating Products And Services When You Search On Heat Treat Buyers Guide.Com
Adapting to new processing demands puts traditional equipment to the test. Can single-chamber solutions keep up, or will applications require different equipment options for efficient processing? In today’s Technical Tuesday, Bryan Stern, product development manager at Gasbarre Thermal Processing Systems, addresses the advantages multi-chamber isolated heat vacuum furnaces bring to the floor.
In the evolving landscape of vacuum heat treatment, single-chamber batch furnaces have long been the cornerstone of material processing. However, with more traditional processes shifting to vacuum, rising energy costs, and increasing environmental pressure, the disadvantages of that approach are emphasized, enhancing the appeal of alternative technologies. Multi-chamber vacuum equipment, while not new to the industry, offers significant solutions to inefficiencies and challenges faced by single-chamber systems. With advances in technology, improved operational planning, and an increasingly competitive market, multi-chamber isolated heat furnaces are becoming a more viable choice.
What Is an Isolated Heat Vacuum Furnace?
An isolated heat vacuum furnace keeps the heat chamber separate from the ambient atmosphere throughout the process, including loading and unloading. This allows the heated zone to maintain a stable temperature and vacuum between cycles, unlike single-chamber furnaces, which must heat up and cool down for each new load. Key components of this furnace type include an additional evacuation chamber, a dynamic sealing door, and a mechanism for moving the workload between chambers. While multi-chamber isolated heat furnaces may be batch or continuous, the above features fundamentally distinguish them from single-chamber batch equipment. This difference is more than just a technical nuance; it has profound implications for operations and efficiency.
The widespread use of single-chamber vacuum furnaces has significantly shaped the design and operation of vacuum furnaces today. But it is important to remember some of the challenges to this approach that we often take for granted.
Energy Efficiency Has Entered the Chat
Single-Chamber Challenge
In single-chamber systems, the entire furnace must go through a full cycle of loading, evacuation, ramping, soaking, cooling, and unloading for every batch of parts. This adds significant “dead time” on either side of the thermal process. In addition to pump-down time, ramping from room temperature typically adds 1–2 hours to the cycle time before soaking which creates a barrier to throughput. Another drawback is that the energy required to heat the furnace is thrown away after every cycle. Due to the high thermal capacity of materials like graphite and molybdenum, this is not inconsequential. With 100% thermal efficiency defined as only consuming the energy required to heat the work and fixturing, single-chamber batch furnaces typically operate in a thermal efficiency range of around 30%–50%.
Isolated Heat Advantage
In an isolated heat furnace, the work zone remains at temperature and the energy required to heat the furnace is not thrown away. Additionally, the introduction of work to a preheated work zone allows the load to be heated more quickly, reducing the time required to achieve temperature and reducing holding losses. While multi-chamber batch furnaces experience some savings, they still consume excess energy since the heat cage is empty during unloading, loading, and evacuation. Continuous configurations, however, see significant improvement with only holding losses and the energy required to heat the work and fixturing being consumed. These advantages mean that continuous furnaces typically operate in a thermal efficiency range of 45%–65%. The result is a 15%–35% energy efficiency improvement over the majority of existing equipment.
The tension of designing a single-chamber furnace to handle both heating and cooling in the same space presents substantial challenges. Insulation pack thickness is often limited to balance the need for quick pump-down. Gas nozzle penetrations through the insulation pack create direct radiation losses. This erodes thermal efficiency, adds thermal mass, and restricts gas flow during cooling. These conflicting design priorities often lead to unsatisfactory compromises and fluctuating designs. Between the additional energy to heat and cool and increase power demand at temperature, there are a lot of energy savings being left on the table.
Isolated Heat Advantage
Because the heating and cooling take place in separate locations, multi-chamber isolated heat equipment benefits from the ability to have dedicated designs tailored at each work position. More insulation can be used as conditioning time is not a significant consideration. Additionally, the insulation can be designed without penetrations, further reducing losses. Moving the work to a dedicated cooling position removes restrictions to gas flow and allows the work to radiate directly to the cold wall. This is especially beneficial at the beginning of a quench when the work is at high temperature. This can allow cooling rates to be achieved with lower quench pressures and smaller quench motors.
Thermal Cycling: Here We Go Again . . .
Single-Chamber Challenge
A single-chamber furnace must be built to endure extreme thermal cycling again . . . and again. This requires detailed design consideration to account for thermal shock, expansion, ratcheting, creep, and low-grade oxidation — all of which contribute to maintenance and replacement cost for expensive, long lead refractory components.
Isolated Heat Advantage
Since the heated portion of the furnace remains at stable temperature and vacuum, internal components are not subject to the same destructive forces. An isolated heat cage can remain in service much longer before requiring service or replacement. It also decreases the likelihood of sudden and unexpected equipment failure. Increasing the lifespan of the most expensive consumable assembly in the furnace is an incredibly valuable advantage that is frequently overlooked.
Find more on this topic in Heat Treat Radio episode #110. Bryan discusses the shift from single-chamber batch furnaces to isolated heat vacuum furnaces and speaks to some of the advantages mentioned in this article. Click the image to watch, listen, and learn on Heat Treat Radio.
Throughput and Load Size: Can They Help?
Single-Chamber Challenge
Single-chamber batch vacuum processing is notorious for the long cycle times and resulting limited throughput. One way to reduce the costs of the wasted energy and dead time is to increase the load size to distribute the cost over more work. While this can increase capacity and reduce the cost per part, it is counterproductive to many objectives of the heat treating process. As the load size increases, it becomes more difficult to maintain thermal and process uniformity across parts at the surface versus the center of the load. This is especially problematic for densely packed loads. Loads take longer to soak out to a uniform temperature, extending cycle times. Similarly, it is difficult to achieve rapid and uniform cooling rates which can lead to higher quench pressures, larger cooling motors, or underutilizing the work envelope.
Isolated Heat Advantage
While multi-chamber batch isolated heat furnaces experience many of the other advantages discussed in this article, throughput is where continuous configurations really shine. Because separate loads are being processed simultaneously, similar or greater throughputs can be achieved with much smaller load sizes. For instance, a process with a two-hour soak would typically require around a five-hour total cycle time in a single-chamber furnace. That same process could be segmented in a continuous furnace indexing loads in as little as 15 minutes, depending on the configuration of the equipment (see Figure 3). With a throughput ratio of 20:1, each load would only need to be 1/20th of the batch load to achieve the same throughput. With these mechanics, it quickly becomes apparent how continuous processing is capable of achieving much greater throughput while benefiting from the uniformity of smaller load sizes as well as the other advantages discussed.
Increasing the capacity of a single-chamber production line necessitates adding additional discrete furnaces. This means that all of the equipment systems are duplicated. Each furnace means another chamber, pumping system, manifolds, quench motor, VFD, control cabinet, certifications, instrument calibrations, etc. There really is no economy of scale available to help facilitate high volume production.
Isolated Heat Advantage
For most processes, increasing the capacity of a continuous multi-chamber furnace only requires adding additional heated work positions to shorten the index rate. All other auxiliary equipment and infrastructure can serve double-duty, and redundant systems and maintenance are avoided. This applies the cost directly to the necessary equipment (heat cage, elements, power supply, etc.). The resulting economy of scale often makes continuous equipment a far greater value proposition for high-volume applications that would otherwise require multiple furnaces.
Vacuum Performance: Don’t Reduce Me Like That!
Single-Chamber Challenge
Because single-chamber batch furnaces are exposed to air and humidity between each cycle, they require a higher vacuum (i.e., lower pressure) to achieve the purity required for a given process. This is because even though the furnace is evacuated to a low pressure, the remaining atmosphere is still primarily comprised of oxidizers in the form of residual air and water molecules desorbing from the internal surfaces of the furnace. Achieving the high vacuum levels required to achieve the necessary reducing atmosphere in a reasonable time can result in additional pumping equipment such as a booster or diffusion pump. This adds to system complexity, upfront cost, maintenance, and operating cost. Unfortunately, vacuum processes are often developed in, and organized around, single-chamber batch processing, so the actual purity requirement often gets distilled into an ultra-low vacuum level on the process specification. Consequently, these aggressive vacuum specifications are carried over to other types of equipment where they may not be necessary to achieve the same results.
Isolated Heat Advantage
Because the heat cage remains under vacuum throughout the process, there is less exposure to atmospheric contaminants. This allows oxidizing constituents to decay to very low levels leading to improved vacuum purity. Even though the absolute pressure is higher, the makeup of the remaining atmosphere is primarily inert. Given time for desorption to decay, it is entirely possible to have a purer environment at a higher pressure without requiring the complex pumping systems necessary in a single-chamber batch furnace. Reduction levels associated with diffusion pumping in single-chamber furnaces can be achieved at higher pressures with a two-stage or even single-stage pumping systems in an isolated heat furnace. This is one of the most overlooked and misunderstood advantages of isolated heat processing.
The Shift Toward Isolated Heat Furnaces
Despite the many challenges associated with single-chamber batch processing, the prevalence of these furnaces has remained high due to their simplicity and familiarity. So, why are multi-chamber furnaces gaining traction now?
“There is a pending perfect storm of market conditions poised to tip the scales.”
There is a pending perfect storm of market conditions poised to tip the scales. More and more traditional processes are shifting to vacuum for its long list of advantages, including tighter process control, flexibility, safety, insurance liability, and improved working environment, just to name a few. This push to convert more processes is driving a need to optimize efficiency and improve cost. The existing approach has known intrinsic inefficiencies and a limited growth path for improvement.
As more heat treaters either experience or compete with the benefits of multi-chamber isolated heat equipment, adoption will continue to accelerate.
Challenges and Considerations
While isolated heat furnaces offer numerous advantages, they are not without challenges. These systems are more complex, require a detailed specification process, and may not be suitable for very large components, intermittent operations, or applications requiring a high degree of flexibility. Many of the advantages of multi-chamber equipment show up in operating and maintenance costs. These benefits can be missed if these costs are not properly accounted for in the ROI analysis phase. Overemphasizing upfront costs can mean missing out on a much better return on investment for equipment with installation life in the range of 20–30 years.
Applications and Future Prospects
Isolated heat vacuum furnaces are not industry specific; rather, they offer advantages across a wide range of applications. Processes characterized by short cycle times benefit because a greater percentage of the floor-to-floor time is dead time and can be recovered, improving equipment utilization. Processes characterized by long cycle times benefit because they can be segmented and indexed at much faster rates, increasing throughput. Surface treatments can benefit from the process uniformity of smaller load sizes without sacrificing throughput. High-volume production environments, in particular, stand to gain the most. Whenever there is a need for more than one batch furnace or where there are numerous small parts in a large work zone, the efficiency and cost savings of continuous isolated heat furnaces truly stand out.
Conclusion
The industry’s focus on efficiency, reduced emissions, and lower operating costs makes isolated heat vacuum furnaces a promising direction for the future. While single-chamber furnaces will still have their place, isolated heat furnaces are becoming more prevalent for many heat treatment processes. Offering superior energy efficiency, better process control, and a more sustainable approach to thermal processing, these furnaces will enable manufacturers to provide high quality, cost-effective solutions that meet today’s market demands and future challenges.
About the Author:
Bryan Stern Product Development Manager Gasbarre Thermal Processing Systems
Bryan Stern has been involved in the development of vacuum furnace systems for the past eight years and is passionate about technical education and bringing value to the end-user. Currently product development manager at Gasbarre Thermal Processing Systems, Bryan holds a B.S. in Mechanical Engineering from Georgia Institute of Technology and a B.A. in Natural Science from Covenant College. In addition to being a member of ASM, ASME, and a former committee member for NFPA, Bryan is a graduate of the MTI YES program and recognized in Heat Treat Today’s40 Under 40 Class of 2020.
The heat treat industry is rich with knowledgeable leaders, resourceful problem solvers, and innovative teams. One of our favorite things to do here atHeat Treat Today is to draw attention to the wealth of expertise in the field, so we are pleased to launch the Voices in Heat Treat series, pointing readers to a treasure house of recorded interviews and discussions diving into the fundamentals of thermal processing.
In this and coming articles drawn from the audio library at Solar Atmospheres, we will summarize topics on everything from basic heat treating how-tos, preventative maintenance, and troubleshooting to the history of hot zone designs, temperature uniformity surveys, and the distinctions to take into consideration when processing different kinds of metals and alloys. In today’s installment, our industry experts focus on vacuum brazing and the uniqueness of heat treating titanium.
In the premiere article of this series, Bill Jones, founder and CEO of Solar Atmospheres and Solar Manufacturing, interviews industry leaders about the advantages of vacuum furnace brazing. Read the highlights of their discussion about the process, in particular when used with stainless steel and titanium. The summary of a fourth episode recorded earlier has been added, expanding on the topic of the advantages of processing titanium in a vacuum furnace. The experts are Calvin Amenheuser, vice president of the Hatfield plant, and Mike Paponetti, sales manager of the southeast. Jim Nagy, senior vice president of Solar Manufacturing, hosts the episodes. A summary of each conversation is below, followed by links that will take you directly to that podcast episode.
Bill Jones and the Team Speak on Vacuum Brazing, a 3-Part Series
“Advantages of Vacuum Furnace Brazing”
December 2015
Brazing to form strong metallurgical bond where the brazed joint becomes a sandwich of different layers, each linked at the grain level
This episode is the first in a series on vacuum furnace brazing, with an overview of different types of brazing processes and why vacuum furnace brazing is superior to other joining methods, particularly torch brazing and welding.
The conversation explores various reasons why a vacuum furnace is well-suited to perform brazing because it provides:
a controlled, consistent atmosphere cycle after cycle
uniform heating throughout the hot zone
a controlled rate of heating
the elimination of air to prevent the formation of oxidation of the metal
Vacuum Furnace Brazing vs. Alternative Methods
Both Cal Amenheuser and Mike Paponetti speak about vacuum brazing being a superior process to alternative methods. Mike noted that torch brazing is effective for low volume loads, but the process risks flux entrapment and could produce messy, overheated and possibly carburized parts. In contrast, vacuum furnace brazing allows for higher volume loads, providing a repeatable process, precise temperature measurements, and versatility.
Brazing applications from parts to rockets
Calvin added that while welding melts the materials and produces a strong joint, the surrounding material is weaker. With vacuum furnace brazing, the brazed joint is just as strong or stronger afterward as before.
Finally, the panelists compared how batch vacuum furnace brazing eliminates distortion that is typical with torch brazing and welding because of hot zone uniformity. A batch furnace operator can modify the process to meet the demand of the load, and furnace charts provide proof of reveal what exactly happened during the run so that successful recipes can be repeated.
In this episode, second in the series on the vacuum furnace brazing, the Solar team reconvened to discuss advantages of and concerns with nickel-based and copper-based brazing alloys.
All agree that nickel-based alloy offers a cleaner braze but emphasize precautions must be put in place to avoid metal erosion and cracking. While readily available and a good match for low carbon steel, copper flashes during the braze. Inert gas is recommended to decrease evaporation of the copper-based alloy.
“Processing Titanium in Vacuum Furnaces: Active Brazing of Titanium in a Vacuum Furnace”
April 2016
In this third and final episode on the topic of vacuum furnace brazing, Bill Jones, Calvin Amenheuser, and Mike Paponetti consider significant challenges to brazing titanium, which is the need to reduce surface oxide to allow the process to take place and why active brazing is suggested as a means to meet that challenge. What follows is an informative discussion on composites that allow producing companies add to the material, like hydrated titanium, zirconium, and indium, to help overcome oxides, which are effective at wedding to the surface.
“Processing Titanium in Vacuum Furnaces: Advantages”
February 2013
175,000 pounds of 6Al-4V titanium in Solar’s 48-foot-long vacuum furnace
Although recorded earlier than and thus separately from the series on vacuum furnace brazing, this summary of an episode is included in this article to provide context about the advantages of processing titanium in a vacuum furnace. This is a solo Bill Jones episode.
Bill Jones highlights how vacuum furnaces provide a pure atmosphere for processing titanium compared to an argon atmosphere, saving machining costs and time. Additionally, vacuum processing uses forced inert gas quenching to cool titanium as opposed to water quenching which results in a more uniform result and eliminates part distortion. Finally, fixturing parts properly in a vacuum furnace with graphite allows heat treaters to preserve the part shape and avoid movement.
Bill Jones Founder & CEO Solar Atmospheres, Solar Manufacturing Source: Solar AtmospheresCalvin Amenheuser Vice President of Operations, Souderton plant Solar Atmospheres Source: Solar AtmospheresMichael Paponetti Sales Manager of the Southeast Solar Atmospheres, Inc. Source: Solar AtmospheresJim Nagy Senior Vice President Solar Manufacturing, Inc. Source: LinkedIn
The Heat Treat Doctor® ha vuelto para ofrecer sabios consejos a los lectores de Heat Treat Today y para responder a suspreguntas sobre el tratamiento térmico, brazing, sinterizado y otros tipos de procesamiento térmico, así como preguntassobre metalurgia, equipos y problemas relacionados con los procesos.
The Heat Treat Doctor® has returned to offer sage advice to Heat Treat Today readers and to answer your questions about heat treating, brazing, sintering, and other types of thermal treatments as well as questions on metallurgy, equipment, and process-related issues.
This article was originally published inHeat Treat Today‘sSeptember 2024 People of Heat Treat print edition.
El temple es un paso fundamental en el proceso de tratamiento térmico. Y si bien el especialista en tratamiento térmico suele tener varias opciones disponibles, existe un delicado equilibrio entre lo que está disponible para nosotros y cómo podemos optimizar sus características de rendimiento para cumplir con los requisitos/especificaciones de nuestros clientes. Se deben tener en cuenta cuidadosamente el material, el diseño de la pieza (geometría), los requisitos previos y posteriores de manufactura, la carga, el cambio dimensional permitido (es decir, la distorsión) y el proceso como tal. Conozcamos más.
Medios de temple: una breve Descripción
Los medios de temple actuales ofrecen una amplia gama de capacidades que, en algunos casos, se traslapan. Sin embargo, en un nivel fundamental, la función de un medio de temple es extraer calor de la superficie de la pieza para cumplir con una velocidad crítica de enfriamiento especificada y con ello lograr la microestructura necesaria para lograr las propiedades mecánicas y físicas requeridas. En el temple de aceros, por ejemplo, se debe evitar pasar por la “nariz” de la curva de transformación-tiempo-temperatura (TTT) si el resultado final deseado es una microestructura martensítica (o bainítica). Por el contrario, la velocidad de enfriamiento para un proceso de normalización requiere enfriamiento “al aire”, un término que a menudo se malinterpreta y que abordaremos en una discusión futura.
Figura 1. Medios de Temple comunes y su efecto en la distorsión (1)
Sin embargo, un medio de temple (Figura 1) es más que solo su velocidad de enfriamiento. Los medios de temple deben ser estables durante su vida útil, especialmente con respecto a la degradación (por ejemplo, oxidación), ser seguros, ser fáciles de arreglar y mantener, tener un alto punto de vaporización, idealmente no interactuar con la superficie de la pieza, usarse dentro de su rango de rendimiento óptimo, tener una larga vida útil, eliminarse fácilmente mediante limpieza después del temple y ser rentables.
A manera de una caracterización muy amplia, los medios de temple se pueden dividir en las siguientes categorías generales:
Medios de temple líquidos (p. ej., a base de agua, aceites, polímeros, sales fundidas y metales fundidos)
Medios de temple gaseosos (p. ej., aire, nitrógeno, argón, hidrógeno, vapor, dióxido de carbono, dióxido de azufre, gases reductores, atmósferas protectoras sintéticas o generadas, gases a alta presión)
Medios de temple sólidos (p. ej., dados de prensa enfriados, placas y polvos)
Medios de medios mixtos (p. ej., temple por aspersión, lechos fluidizados)
Figura 2. Diagrama de Ishikawa (también conocido como de pescado) de las variables de temples (1)
Selección del medio de temple óptimo
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Se deben tener en cuenta varios factores al seleccionar el mejor medio de temple. A continuación, se enumeran algunos de los aspectos importantes a tener en cuenta al seleccionar el medio adecuado (Figura 2):
Material: composición química, templabilidad, forma (p. ej., barra, placa, forja, fundición), tipo (p. ej., forjado, sinterizado) y limpieza, por nombrar algunos
Geometría/diseño de la pieza: forma, tamaño, peso, complejidad
Estado de laminación o tratamiento térmico previo: recocido, normalizado, preendurecido, relevado de esfuerzos
Estado de tensión: el efecto acumulativo de las operaciones de laminación y las operaciones de fabricación del cliente antes del tratamiento térmico
Carga: canastillas (aleación, compuesto C/C, placas de grafito, etc.)
Parámetros del proceso: temperatura, tiempo, precalentamiento
Selección del equipo: ¿es óptimo o simplemente adecuado para el trabajo?
Medio(s) de temple disponibles: sus limitaciones y ventajas
Es importante hablar brevemente aquí sobre dos aspectos del proceso de selección del medio de temple. Primero, observar la diferencia entre dureza y templabilidad (que analizaremos con más detalle en el futuro). Los tratadores térmicos tienden a centrarse en la dureza (ya que podemos medirla fácilmente en nuestro taller), pero la templabilidad es una consideración crítica en la selección del medio de temple. La templabilidad es una propiedad del material independiente de la velocidad de enfriamiento y dependiente de la composición química y el tamaño del grano. Cuando se evalúa mediante pruebas de dureza, la templabilidad se define como la capacidad del material bajo un conjunto dado de condiciones de tratamiento térmico para endurecerse “en profundidad”. En otras palabras, la templabilidad se relaciona con la “profundidad de endurecimiento”, o el perfil de dureza obtenido, no con la capacidad de alcanzar un valor de dureza particular. Cuando se evalúa mediante técnicas microestructurales, la templabilidad se define (para aceros) como la capacidad del acero para transformarse parcial o completamente de austenita a un porcentaje definido de martensita.
Tabla 1. Valores medios e instantáneos del coeficiente de transferencia de calor (3)
En segundo lugar, se debe tener en cuenta tanto el valor medio como el instantáneo del coeficiente de transferencia de calor alfa (α) del medio de temple. Aunque la “potencia” máxima de temple se puede describir mediante el coeficiente de transferencia de calor instantáneo, el coeficiente de transferencia de calor promedio (Tabla 1) proporciona una mejor comparación relativa de los diversos medios de temple, ya que representa el valor del coeficiente de transferencia de calor en todo el rango de enfriamiento (desde el inicio hasta el final del temple). Es importante recordar que la capacidad de gestionar (no controlar) la distorsión es un delicado acto de equilibrio entre la extracción uniforme del calor y la transformación adecuada.
Tabla 2. Clasificación de los aceites de temple (1)
Un ejemplo común: selección de aceite de temple
Los factores importantes a tener en cuenta al seleccionar un aceite de temple, que son válidos en una forma ligeramente modificada para la mayoría de los medios líquidos, son: el tipo de medio (es decir, características del temple, datos de la curva de enfriamiento, nuevo y a lo largo del tiempo); velocidad de temple (consulte a Tabla 2); temperatura de uso; volumen efectivo del tanque de enfriamiento [es decir, la regla de un galón por libra de acero (8,4 L/kg)]; y los requisitos del cliente.
Los factores de diseño del tanque de temple también juegan un papel importante e involucran lo siguiente:
Volumen de aceite en el tanque de temple
Número de recirculadores o bombas
Ubicación de los recirculadores
Tipo de recirculadores (velocidad fija ovariable)
Disposición de los deflectores internos del tanque (tubos de aspiración, álabes de flujo direccional, etc.)
Diseño del elevador de temple (es decir, restricciones de flujo)
Dirección del flujo del temple (hacia arriba o hacia abajo a través de la carga)
Tamaño de la propela (diámetro, espacio libre en el tubo de aspiración)
Máximo incremento dela temperatura (diseño) delaceite después del temple
Altura del aceite sobre la carga
Intercambiador de calor: tipo, tamaño, tasa de extracción de calor (BTU instantáneos/minuto)
Tiempo de recuperación del aceite hasta el set point
Por último, se deben tener en cuenta factores como: la masa de la pieza; la geometría de la pieza (por ejemplo, secciones delgadas y gruesas, esquinas y barrenos afilados, perfil de los dientes del engrane, perfil de la rosca, etc.); espaciamiento de la pieza en la carga; velocidad de flujo efectiva a través del área de temple (vacía y con carga); estado de tensión de operaciones anteriores (de manufactura); operaciones de tratamiento térmico posteriores a realizar (si las hay); carga, incluidas las charolas, las canastillas y el herramental (material y diseño); y el material (composición química y templabilidad).
Reflexiones finales
El temple, considerado por muchos como un tema complejo y multifacético, es un asunto que los especialistas en tratamiento térmico deben supervisar y controlar constantemente. En futuras entregas, analizaremos muchos de los aspectos individuales del temple. Lo importante aquí es reconocer que, si se realiza correctamente, el temple (en cualquier forma) optimizará un tratamiento térmico determinado y ayudará a producir las piezas de la más alta calidad que exigen las industrias a las que prestamos nuestros servicios.
Referencias
Daniel Herring, Atmosphere Heat Treatment, Volume II: Atmospheres | Quenching | Testing (BNP Media Group, 2015).
Bozidar Liscic et al., Quenching Theory and Technology, Second Edition (CRC Press, Taylor Francis Group, 2010).
Daniel Herring, “A Review of Gas Quenching from the Perspective of the Heat Transfer Coefficient,” Industrial Heating, February 2006.
Sobre el autor
Dan Herring “The Heat Treat Doctor” The HERRING GROUP, Inc.
Dan Herring ha trabajado en la industria durante más de 50 años y ha adquirido una vasta experiencia en campos que incluyen ciencia de materiales, ingeniería, metalurgia, investigación de nuevos productos y muchas otras áreas. Dan es autor de seis libros y más de 700 artículos técnicos.
Para más información: Comuníquese con Dan en dherring@heat-treat-doctor.com.
For more information about Dan’s books: see his page at the Heat Treat Store.
Find Heat Treating Products And Services When You Search On Heat Treat Buyers Guide.Com
The Heat Treat Doctor® has returned to offer sage advice to Heat Treat Today readers and to answer your questions about heat treating, brazing, sintering, and other types of thermal treatments as well as questions on metallurgy, equipment, and process-related issues.
The Heat Treat Doctor® ha vuelto para ofrecer sabios consejos a los lectores de Heat Treat Today y para responder a suspreguntas sobre el tratamiento térmico, brazing, sinterizado y otros tipos de procesamiento térmico, así como preguntassobre metalurgia, equipos y problemasrelacionados con los procesos.
This article was originally published inHeat Treat Today‘sSeptember 2024 People of Heat Treat print edition.
Quenching is a critical step in the heat treating process. And while there are often several choices available to the heat treater, a delicate balance exists between what is available to us and how we can optimize its performance characteristics to meet our client’s requirements/specifications. Material, part design (geometry), pre-and post-manufacturing requirements, loading, allowable dimensional change (i.e., distortion), and the process itself must be taken into careful consideration. Let’s learn more.
Quenchants — A Brief Overview
Today’s quenchants offer a broad and, in some instances, overlapping range of capabilities. But at a fundamental level, the role of a quenchant is to extract heat from the part surface to meet a specified critical cooling rate and achieve the desired microstructure in the component part necessary to achieve the required mechanical and physical properties. In hardening of steels, for example, one must miss the “nose” of the time-temperature transformation (TTT) curve if the desired end-result is a martensitic (or bainitic) microstructure. By contrast, the cooling rate for a normalizing process requires cooling in “still air” — a term that is often misunderstood and which we will cover in a future discussion.
Figure 1. Common types of quenchants and their effect on distortion (See Reference 1)
However, a quenchant (Figure 1) is more than just its cooling rate. Quenchants should be stable over their service life, especially with respect to degradation (e.g., oxidation), be safe, be easy to service and maintain, have a high vaporization point, ideally not interact with the part surface, be used within their optimum performance range, have long life, be easily removed by cleaning after quenching, and be cost effective.
As a very broad-based characterization, quenchants can be divided into the following general categories:
Mixed media quenchants (e.g., mist or fog quenching, fluidized beds)
Figure 2. Ishikawa (aka fishbone) diagram of quenching variables (See Reference 1)
Selection of the Optimal Quench Medium
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Various factors must be taken into consideration when selecting the best quench medium. The following are some of the important considerations when selecting the proper quench medium (Figure 2):
Material — chemistry, hardenability, form (e.g., bar, plate, forging, casting), type (e.g., wrought, powder metal), and cleanliness to name a few
Part geometry/design — shape, size, weight, complexity
Mill or preheat treatment condition — annealed, normalized, pre-hardened, stress-relieved
Stress state — the cumulative effect of both mill operations and customer manufacturing operations prior to heat treatment
Process parameters — temperature, time, preheating
Equipment selection — is it optimal or simply adequate for the job?
Quench medium(s) available — their limitations as well as their advantages
It is important to talk briefly here about two aspects of the quench medium selection process. First, note the difference between hardness and hardenability (which we will discuss in more detail in the future). Heat treaters tend to focus on hardness (since we can easily measure it in our shops), but hardenability is a critical consideration in quench medium selection. Hardenability is a material property independent of cooling rate and dependent on chemical composition and grain size. When evaluated by hardness testing, hardenability is defined as the capacity of the material under a given set of heat treatment conditions to harden “in-depth.” In other words, hardenability is concerned with the “depth of hardening,” or the hardness profile obtained, not the ability to achieve a particular hardness value. When evaluated by microstructural techniques, hardenability is defined (for steels) as the capacity of the steel to transform partially or completely from austenite to a defined percentage of martensite.
Table 1. Average and instantaneous values of the heat transfer coefficient (See Reference 3)
Second, one must be aware of both the average and instantaneous value of the heat transfer coefficient alpha of the quench medium. Although the maximum quenching “power” may be described by the instantaneous heat transfer coefficient, the average heat transfer coefficient (Table 1) provides a better relative comparison of the various quenching media since it represents the value of the heat transfer coefficient over the entire range of cooling (from the start to the end of quenching). It is important to remember that the ability to manage (not control) distortion is a delicate balancing act between uniform heat extraction and proper transformation.
A Common Example — Quench Oil Selection
Important factors to consider when selecting a quench oil, which hold true in a slightly modified form for most liquid quenchants, are: the type of quenchant (i.e., quench characteristics, cooling curve data — new and over time); quench speed (see Table 2); usage temperature; effective quench tank volume (i.e., the one gallon per pound of steel [8.4 L/kg] rule); and the client’s requirements.
Table 2. Classification of quench oils (See Reference 1)
Quench tank design factors also play an important role and involve the following:
Volume of oil in the quench tank
Number of agitators or pumps
Location of agitators
Type of agitators (fixed or variable speed)
Internal tank baffle arrangement (draft tubes, directional flow vanes, etc.)
Quench elevator design (i.e., flow restrictions)
Quenchant flow direction (up or down through the load)
Propeller size (diameter, clearance in draft tube)
Maximum (design) temperature rise of the oil after quenching
Finally, consideration must be given to factors such as: part mass; part geometry (e.g., thin and thick sections, sharp corners and holes, gear tooth profile/modulus, thread profile, etc.); part spacing in the load; effective flow velocity through the quench area (empty and with a load); stress state from prior (manufacturing) operations; post heat treat operations to be performed (if any); loading including the grids, baskets, and fixture (material and design); and the material (chemistry and hardenability).
Final Thoughts
Quenching, considered by many to be a complex and multi-faceted subject, is one heat treaters must constantly monitor and control. In future installments we will be discussing many of the individual aspects of quenching. What is important here is to recognize that done correctly, quenching (in whatever form) will optimize a given heat treatment and help produce the highest quality parts demanded by the industries we serve.
References
Daniel Herring, Atmosphere Heat Treatment, Volume II: Atmospheres | Quenching | Testing (BNP Media Group, 2015).
Božidar Liščić et al., Quenching Theory and Technology, Second Edition (CRC Press, Taylor Francis Group, 2010).
Daniel Herring, “A Review of Gas Quenching from the Perspective of the Heat Transfer Coefficient,” Industrial Heating, February 2006.
About the Author
Dan Herring “The Heat Treat Doctor” The HERRING GROUP, Inc.
Dan Herring has been in the industry for over 50 years and has gained vast experience in fields that include materials science, engineering, metallurgy, new product research, and many other areas. He is the author of six books and over 700 technical articles.
On just about any given Tuesday, Heat TreatToday features an article that aims to educate our heat treating readers — be it in a process, equipment, metals, analysis, critical parts, or more. On this Thursday, enjoy this sampling of Technical Tuesday articles from the past several months.
Case Study: Heat Treat Equipment Meets the Future Industry Today
How has one heat treat furnace supplier contended with modern challenges of manufacturing? In this case study about a shift away from traditional forms of heat treat, explore how vacuum furnace technology has more technological horizons to bound.
Figure 1. Construction and schematic furnace cross-section CMe-T6810-25
Several key features discussed are the various challenges that characterize modern industry; the differences between historical heat treat furnaces and vacuum furnaces; furnace features that can meet these obstacles; and a close look at what one equipment option from SECO/WARWICK can offer. Additionally, explore the case study of a process that resulted in the following assessment: All technological requirements have been met, obtaining the following indicators of efficiency and consumption of energy factors calculated for the entire load and per unit net weight of the load (700 kg).”
How do thermocouples work? How would you tell if you had a bad one? Those ever-present temperature monitors are fairly straightforward to use, but when it comes to how it works — and why — things get complicated.
Figure 2. Eric Yeager of Cleveland Electric Laboratories explaining the 101 of all things thermocouple
This transcript Q&A article was published in a print edition, but there was too much information to fit the pages. Click below to read the full-length interview, including the final conversation about how dissimilar metals create electromotive force (EMF). Included in the discussion is proper care of T/C and guidance on when it’s time to replace.
A Quick Guide to Alloys and Their Medical Applications
Figure 3. Sneak peak of this medical alloys resource
If you’re pining for a medical heat treat quick resource in our “off-season,” we have a resource for you. Whether you are a seasoned heat treater of medical application parts or not, you know that the alloy composition of the part will greatly determine the type of heat treat application that is suitable. Before you expand your heat treat capabilities of medical devices, check out this graphic to quickly pin-point what alloys are in high-demand within the medical industry and what end-product they relate to.
The alloys addressed in this graphic are titanium, cobalt chromium, niobium, nitinol, copper, and tantalum.
Resource — Forging, Quenching, and Integrated Heat Treat: DFIQ Final Report
How much time and energy does it take to bring parts through forging and heat treatment? Have you ever tried integrating these heat intensive processes? If part design, forging method, and heat treat quenching solutions are considered together, some amazing results can occur. Check out the report findings when Direct from Forge Intensive Quenching (DFIQTM) was studied.
Figure 4. Examples of DFIQ equipment
Forgings were tested, in three different locations, to see if immediate quenching after forging made a difference in a variety of steel samples. The report shares, “The following material mechanical properties were evaluated: tensile strength, yield strength, elongation, reduction in area, and impact strength. Data obtained on the mechanical properties of DFIQ forgings were compared to that of forgings after applying a conventional post-forging heat treating process.”
3 Top Tips for Brinell and Rockwell Hardness Tests
Figure 5. Testing hardness
Accurate hardness testing is a critical business for numerous industries, not least heat treatment. In this guide, evaluate “best practice” for getting the best possible reading for your hardness test with the most efficiency. These comprehensive tips include proper set up for test equipment and need-to-know information regarding the preparation and execution of both Brinell and Rockwell hardness tests.
In fact, while there are some practices that overlap, knowing the differences is critical to determine whether or not a piece has reached the appropriate hardness. For Brinell, grease may skew a reading so that “at 300 HBW the material may appear 20 HBW softer than it actually is.” On the other hand, the precision in measuring indentation depth (versus indentation width) makes it imperative to keep the surfaces clear of any contamination.
Trending Market Insights for Aluminum Thermal Processing
Figure 6. State of the North American aluminum industry
In this survey on recent and developing changes in the aluminum market, we asked industry players about the impact of trending technology and the overall state of the industry. Their responses to our questions in August 2023 described a steady and increasing melters’ demand; a limited, or lack of, business increase from additive manufacturing and 3D printing; the impact of — and response to — slow supply chains; the status of sustainability in the aluminum market; and how they plan to meet future market demand.
Heat treating aluminum presents a unique concern due to the operating conditions of high temperature, chemical corrosion, mechanical abrasion, and temperature variation. Guest columnist Roger M. Smith, director of technical services at Plibrico Company, LLC, examines the critical role the refractory lining plays in the success of manufacturing aluminum, why a refractory is susceptible to cracking under extreme conditions, and how to select and prepare refractory linings to achieve a longer service life.
A significant concern when manufacturing aluminum metal is the practical service life of the furnace. The service life is driven by the refractory lining’s ability to resist the various operating conditions within the furnace, such as high temperature, temperature variation, chemical corrosion, and mechanical abrasion. Ideally, a single refractory composition would be capable of withstanding all these conditions and readily available at a low price. Unfortunately, this is rarely the case.
Proper refractory selection is often about finding the best balance between price, properties, and performance for the given application and operating conditions. A refractory capable of high strength and abrasion resistance is often susceptible to cracking caused by extreme temperature variations, commonly referred to as thermal shock. However, a material capable of withstanding thermal shock without catastrophic cracking may be vulnerable to chemical corrosion. Finding the best balance of material properties for each zone in each furnace is important for maximizing the service life of a furnace.
Figure 1. Schematic showing refractory lining in an aluminum furnace
Refractory Under Attack — Requirements for Melting Aluminum
The refractory lining in an aluminum furnace (Figure 1) must endure various chemical reactions that occur while the furnace is in operation. There are three separate regions to consider: above, below, and at the melt line. Above the melt line, the refractory must withstand attack from various alkali vapors. Alkali vapors can be produced from flux used in the aluminum and from the combustion products used to heat the furnace. Below the melt line, the refractory must withstand molten aluminum. At the melt line, the region commonly referred to as the bellyband area, there is a triple point where the refractory, atmosphere, and aluminum interact.
The refractory below the melt line comes in direct contact with liquid aluminum when the furnace is in operation. This contact can create a chemical reaction zone where oxides on the surface of the refractory can be reduced, such as silica (SiO2) to form silicon. Conversely, aluminum can penetrate into the refractory lining either through the same redox reactions or through infiltration due to capillary forces.
Aluminum forms corundum (Al2O3) when it oxidizes. This results in a change of the crystal structure from face-centered cubic to hexagonal, which causes a significant volume expansion. When corundum is formed inside the refractory lining, the change in volume creates cracks, which lead to more infiltration and more cracks until the refractory lining ultimately fails.
Wetting the Refractory
One method for reducing the reaction zone is to prevent the aluminum from “wetting” the refractory (see Figure 2). A liquid’s ability to “wet” a surface is defined by the contact angle of the liquid. When the contact angle between the liquid and the surface is greater than 90 degrees, then the liquid is said to wet the surface. When the contact angle is less than 90 degrees, the liquid does not wet the surface. A liquid that does not wet the surface is analogous to water beading on a car that has been freshly waxed. When aluminum does not wet a refractory, it is not able to react with the refractory and is not able to penetrate the lining.
Figure 2. Contact angle of the liquid demonstrating wetting vs. non-wetting
Various additives can be used to reduce aluminum’s tendency to wet a refractory. Some of the most used additives include barium, boron, or fluoride. They modify the surface chemistry of the refractory and reduce aluminum’s ability to react and penetrate. Using additives such as these greatly extends the effective service life of a refractory lining.
While non-wetting additives can be beneficial to extending the service life in areas where there is contact with molten aluminum, there are no benefits when not in aluminum contact. They do not protect from alkali attacks above the melt line. They do not enhance the abrasion resistance of the material. They do not improve the thermal shock resistance of the material. Furthermore, these additives are volatile. When exposed to temperatures above 1700°F (927°C), they begin to lose their effectiveness because they chemically react with other materials in the refractory and change. The additives can also be costly, which raises the price of the refractory compared to one with the same composition but without the additive.
The presence of non-wetting additives can have some negative effects on a refractory. Tests have shown that a 1% addition of a fluoride additive in a conventional castable can reduce the hot modulus of rupture (HMOR) by as much as 30% at 2000°F (1093°C). The effect can be even more significant in a low-cement castable. The loss in hot strength is likely attributed to the formation of a glassy phase induced by the additive. Fluoride and boron are both well-known glass formers and will form a glassy phase at the grain boundaries at high temperatures, which reduces the bond strength between individual grains and the overall strength of the bulk material.
Figure 3. Refractory lining
Balancing Refractory Properties
The advantages and disadvantages of a refractory material should be considered when selecting materials for an aluminum furnace. The sidewalls of a furnace all come in direct contact with molten aluminum.
The upper sidewalls must be scraped to remove aluminum that splashes up to prevent corundum growth. The refractory selected for its sidewalls should be abrasion resistant to protect from mechanical scraping and non-wetting to protect from corundum growth. The hearth and well are submerged in aluminum, but they do not see the same level of abrasion as the sidewalls. The sub-hearth may see some molten aluminum but must also provide support, so a strong, non-wetting refractory should be used.
The door and sill will experience temperature fluctuations every time the door is opened, and they will be exposed to abrasion as the furnace is charged. Materials that are resistant to thermal shock and abrasion should be selected. The roof and superstructure need to be strong and resistant to alkali vapors. Backup insulation should be selected to reduce heat loss, but it should be of a composition that has moderate resistance to molten aluminum in case of refractory failure at the hot face.
In all these zones, the operating conditions of the specific furnace must be considered, and the balance of properties must be adjusted case-by-case. The primary failure modes must be identified, and materials should then be adjusted accordingly.
The Key to Refractory Selection
The operating conditions in an aluminum furnace require a refractory lining with different benefits in different zones. At the furnace door, the refractory can experience drastic fluctuations in temperature that can cause cracking. The upper sidewalls will develop scale that has to be scraped off, so the refractory needs to be abrasion resistant.
The lower sidewalls come in direct contact with molten aluminum and need to resist chemical attacks and aluminum penetration to avoid corundum growth. Finding a cost-effective refractory that can meet all these requirements is very difficult, but it can be done with sufficient research. Careful material selection that considers the needs and operating conditions of a particular furnace is important for maximizing the service life of a refractory lining.
About the Author:
Roger M. Smith Director of Technical Services Plibrico Company, LLC Source: Plibrico
Roger Smith is a seasoned professional in the refractory industry. With a master’s degree in Ceramic Engineering from the University of Missouri – Rolla, Roger has over 15 years of experience in the processing, development, and quality assurance of both traditional and advanced ceramics. He has a proven track record in developing innovative ceramic formulations, scaling up processes for commercial production, and optimizing manufacturing operations.
